fac-[Mo(CO)3(1,4,7-trithiacyclodecane)] | 123263-90-1

• 英文名称: fac-[Mo(CO)3(1,4,7-trithiacyclodecane)]
• 英文别名: tricarbonyl(1,4,7-trithiacyclodecane)molybdenum(0)
• CAS: 123263-90-1
• 化学式: C₁₀H₁₄MoO₃S₃
• 分子量: 374.357
• InChiKey: OPOYGCBXRMYSCR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,4,7-三硫杂环癸烷 、 molybdenum hexacarbonyl 以 乙腈 为溶剂， 以61.5%的产率得到fac-[Mo(CO)3(1,4,7-trithiacyclodecane)]
  参考文献：
  名称：

  Grant, Gregory J.; Carpenter, Joseph P.; Setzer, William N., Inorganic Chemistry, 1989, vol. 28, # 22, p. 4128 - 4131

  摘要：

  DOI：

文献信息

• Synthesis and spectroscopic characterisation of tritelluroether, triselenoether, and trithioether complexes of Cr(0), Mo(0) and W(0)
  作者：Andrew J Barton、Julie Connolly、William Levason、Arantza Mendia-Jalon、Simon D Orchard、Gillian Reid

  DOI：10.1016/s0277-5387(00)00425-3

  日期：2000.6

  The complexes fac-[M(CO)(3)L-3] (M = Mo or W, L-3 = MeC(CH2SMe)(3), MeC(CH2SeMe)(3) or MeC(CH2TeMe)(3)) have been prepared from [M(CO)(3)(MeCN)(3)] and characterised by analysis, FAB mass spectrometry, IR, H-1, C-13H-1}, Se-77, Te-125 and Mo-95 NMR spectroscopies. The complexes are prone to decomposition in solution into tetracarbonyls, and attempts to isolate [Cr(CO)(3)L-3] have been unsuccessful. The complexes cis-[Cr(CO)(4)eta(2)-MeC(CH2SMe)(3)}], cis-[Mo(CO)(4)(eta(2)-MeC(CH2SeMe)(3)}] and the robust [M(CO)(4)(S-3)] (M = Cr, Mo or W, S-3 = 1,4,7-trithiacyclononane or 1,4,7-trithiacyclodecane) have been similarly characterised. (C) 2000 Elsevier Science Ltd. All rights reserved.