tris((3,5-dimethylphenyl)(isopropyl)amino)niobium(V) chloride | 361554-20-3

• 英文名称: tris((3,5-dimethylphenyl)(isopropyl)amino)niobium(V) chloride
• CAS: 361554-20-3
• 化学式: C₃₃H₄₈Cl₂N₃Nb
• 分子量: 650.577
• InChiKey: ZKDSEHXKMWZUCF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  tris((3,5-dimethylphenyl)(isopropyl)amino)niobium(V) chloride 生成 tris((3,5-dimethylphenyl)(isopropyl)amino)niobium(IV) chloride
  参考文献：
  名称：

  Dinitrogen Cleavage Stemming from a Heterodinuclear Niobium/Molybdenum N₂ Complex:  New Nitridoniobium Systems Including a Niobazene Cyclic Trimer

  摘要：

  Preparation of the terminal nitrido anion (-)[NNb(N[Pr-i]Ar)(3)] and the niobazene trimer {(mu-N)Nb-(N[Pr-i]Ar)(2)}(3) (Pr-i = CH(CH3)(2) or CH(CD3)(2), Ar = 3,5-C6H3Me2) entails cooperative splitting of dinitrogen upon reduction of the heterobimetallic paramagnetic dinitrogen complex (Ar[R]N)(3)Mo(mu-N-2)Nb(N[Pr-i]Ar)(3) (R = Bu-t or C(CD3)(2) CH3).

  DOI：

  10.1021/om000159k

文献信息

• Probing the Niobium Metallaaziridine Functionality
  作者：Daniel J. Mindiola、Christopher C. Cummins

  DOI：10.1021/om010089x

  日期：2001.8.1

  Borane abstraction from 4-BH4 was used to access the metallaaziridine-hydride functionality in a niobium system. Unlike its known molybdenum analog, proposed intermediate 4-H displays reactivity characteristic of electrophilic early transition-metal hydride complexes.