(platinum(III))2Cl2(μ-N2H2C(Et))4 | 1224851-97-1

• 英文名称: (platinum(III))2Cl2(μ-N2H2C(Et))4
• CAS: 1224851-97-1
• 化学式: C₁₂H₂₈Cl₂N₈Pt₂
• 分子量: 745.474
• InChiKey: MKGMHZRBCANIRH-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  cis-[(platinum)(NH3)2(NH=C(NH2)Et)2]Cl2 在 O₂ 作用下， 以 乙醇 、 水 为溶剂， 以23%的产率得到(platinum(III))2Cl2(μ-N2H2C(Et))4
  参考文献：
  名称：

  Diplatinum(III) [Cl2(μ2-amidinate)4] compound derived from air oxidation of mononuclear cis-[PtII(NH3)2(amidine-κ1)2]2+ complex

  摘要：

  The dinuclear platinum(III) complex [Pt2Cl2{mu(2)-N(H)C(Et)N(H)}(4)] (2) has been prepared by heating cis-[Pt(NH3)(2){NH=C(NH2)Et}(2)](Cl)(2) (cis-1) under aeration conditions in an EtOH/H2O mixture at 70 degrees C for 2 d and it was characterized by elemental analyses (C, H, N), ESI+-MS, IR, H-1 and C-13 NMR spectroscopies and also by X-ray diffraction. Complex 2 represents the second Pt-III dimer stabilized by the amidinate ligand ever known and it has a lantern-type structure with four amidinate ligands bridging two Pt-III centers with Pt-Pt distance of 2.4809(2) angstrom. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2009.08.022