[(η(5)-C5Me5)Ru(1,1'-ferrocenyl-bis(diphenylphosphine))(MeCN)]PF6 | 218158-62-4

• 英文名称: [(η(5)-C5Me5)Ru(1,1'-ferrocenyl-bis(diphenylphosphine))(MeCN)]PF6
• CAS: 218158-62-4
• 化学式: C₄₆H₄₆FeNP₂Ru*F₆P
• 分子量: 976.707
• InChiKey: PYKLABHXMCGZKI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 (permethylcyclopentadienyl)(1,1'-bis(diphenylphosphino)ferrocene)Cl 、 乙腈 以 甲醇 为溶剂， 生成 [(η(5)-C5Me5)Ru(1,1'-ferrocenyl-bis(diphenylphosphine))(MeCN)]PF6
  参考文献：
  名称：

  Pentamethylcyclopentadienyl ruthenium(II) complexes containing chiral diphospines: synthesis, characterisation and electrochemical behaviour. X-ray structure of (η5-C5Me5)Ru{(S,S)-Ph2PCH(CH3)CH(CH3)PPh2}Cl

  摘要：

  Some pentamethylcyclopentadienyl ruthenium(II) diphosphine chloride complexes have been prepared by ligand exchange starting with the parent triphenylphosphine derivatives and their reactivities compared with those of the corresponding cyclopentadienyl compounds. The pentamethyl ligand causes a greater extent of asymmetric induction when the (R)-prophos and (R)-phenphos ligands are used as well as a higher lability of the stereochemistry at the stereogenic ruthenium centre. A shift of about 200 mV in the oxidation potential is caused by the substitution at the penta-hapto ligand. The order of basicity of the diphosphine ligands was also evaluated and was found to be consistent with previous determinations. The crystal structure of(eta(5)-C5Me5)Ru {(S,S)-chiraphos}Cl shows a coordination around the ruthenium atom similar to that found for the (eta(5)-C5H5)Ru{(S,S) -chiraphos}Cl complex. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00219-9