(2-(N,N-dimethylaminomethyl)phenyl)(n-Bu)2SnCl*HCl | 1256962-51-2

• 英文名称: (2-(N,N-dimethylaminomethyl)phenyl)(n-Bu)2SnCl*HCl
• CAS: 1256962-51-2
• 化学式: C₁₇H₃₁Cl₂NSn
• 分子量: 439.056
• InChiKey: WJCCBXGMLJSXBK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  盐酸 、 [2-(N,N-二甲基氨基甲基)苯基]二正丁基锡(IV)氯化物 以 乙醚 、 水 为溶剂， 以97%的产率得到(2-(N,N-dimethylaminomethyl)phenyl)(n-Bu)2SnCl*HCl
  参考文献：
  名称：

  Tri- and diorganostannates containing 2-(N,N-dimethylaminomethyl)phenyl ligand

  摘要：

  The C,N-chelated tri and diorganotin(IV) chlorides react with both protic mineral acids and carboxylic acids. The nitrogen atom of the L-CN ligand (where L-CN is 2-(dimethylaminomethyl)phenyl) is thus quarternized e protonated and new Sn-X bond (X = Cl, Br, I or the remainder of the starting acid used) is simultaneously formed. The set of zwitterionic tri and diorganostannates containing protonated 2-(dimethylaminomethyl) phenyl-moiety was prepared and structurally characterized by multinuclear NMR spectroscopy and XRD techniques. In all these cases, the intramolecular N-H center dot center dot center dot X bond is present in the molecule. Despite the central tin atom remains five-coordinated (except for the [(HLH)-H-CN](+)[(n-Bu)(2)SnCl(NO3)(2)](-)) and reveals a distorted trigonal bipyramidal geometry, the Sn-119 NMR chemical shift values of these zwitterionic stannates are somewhat shifted to the higher field than corresponding starting C, N-chelated tri and diorganotin(IV) halides. Reactions of C,N-chelated organotin(IV) halides with various Lewis acids are also discussed. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.08.006