| 1201912-45-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1201912-45-9
• 化学式: C₂₅H₁₈FN₃OPtS
• 分子量: 622.582
• InChiKey: YTHIATGMJMUHGM-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  a-chloro-b-(2''-phenylpyridine-N'')-dc-[2-(2'-pyridyl)phenyl-N',C]platinum 、 N-(4-fluorophenyl)-N'-benzoyl thiourea sodium salt 以 二氯甲烷 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  Luminescent cyclometallated platinum(II) complexes with N-benzoyl thiourea derivatives as ancillary ligands

  摘要：

  A series of cyclometallated 2-phenylpyridine Pt(II) complexes having N-benzoyl thiourea derivatives as ancillary ligands were prepared and characterised by elemental analysis, IR and UV-Vis spectroscopy, (1)H and (13)C NMR spectroscopy as well as by X-ray diffraction on single-crystal. All complexes were obtained as a single isomer with N atom of the 2-phenylpyridine ligand and S atom of the N-benzoyl thiourea derivatives coordinated in trans positions to the platinum metal as evidenced by using X-ray crystallography and NMR spectroscopy. All Pt(II) complexes show good luminescence properties at room temperature, both in dichloromethane solution and in solid state. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.08.015