dichloro[2-(3,4-dichlorophenyl)imino-κN-N-(2-thiazin-κS-2-yl)thiazolidine]copper(II) | 1290040-72-0

• 英文名称: dichloro[2-(3,4-dichlorophenyl)imino-κN-N-(2-thiazin-κS-2-yl)thiazolidine]copper(II)
• 英文别名: dichloro[2-(3,4-dichlorophenyl)imino-κN-N-(2-thiazin-κN-2-yl)thiazolidine]copper(II)
• CAS: 1290040-72-0；1290040-74-2
• 化学式: C₁₃H₁₃Cl₄CuN₃S₂
• 分子量: 480.756
• InChiKey: AXPUEXJUVZHNAI-BYGZXUDRSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 2-(3,4-dichlorophenyl)imino-N-(2-thiazin-2-yl)thiazolidine 以 乙醇 为溶剂， 以31.4%的产率得到dichloro[2-(3,4-dichlorophenyl)imino-κN-N-(2-thiazin-κS-2-yl)thiazolidine]copper(II)
  参考文献：
  名称：

  Synthesis and structural characterization of two bond isomer copper(II) complexes via molecular modeling coupled with X-ray powder diffractometry

  摘要：

  The reaction of the ambidentate ligand 2-(3,4-dichlorophenyl)imino-N-(2-thiazin-2-yl)thiazolidine (TdTz) with CuCl2 center dot 2H(2)O results in the formation of two new copper complexes, which has been characterized in the solid state by elemental analysis, UV-Vis-NIR diffuse reflectance, electron paramagnetic resonance (EPR) spectroscopy, magnetic measurements, infrared spectroscopy and X-ray powder diffraction. These studies have revealed that the two copper complexes are linkage isomers, which the metal atom is four-coordinated by two chloride ions and one ligand TdTz that act as a N,N bidentate ligand in one case and as a N,S bidentate ligand in the other one. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.01.022