[Cu4(4,6-dimethyl-2-hydroxy-isophthalic acid(3-))2(acetate)2(pyridine)4(methanol)2] | 754981-87-8

• 英文名称: [Cu4(4,6-dimethyl-2-hydroxy-isophthalic acid(3-))2(acetate)2(pyridine)4(methanol)2]
• CAS: 754981-87-8
• 化学式: C₄₆H₄₈Cu₄N₄O₁₆
• 分子量: 1167.09
• InChiKey: OYLIATWURKEVHW-UHFFFAOYSA-F

反应信息

• 作为产物：
  描述：

  [Cu4(4,6-dimethyl-2-hydroxy-isophthalic acid(3-))2(acetate)2(pyridine)4(methanol)2]*2methanol 以 neat (no solvent) 为溶剂， 生成 [Cu4(4,6-dimethyl-2-hydroxy-isophthalic acid(3-))2(acetate)2(pyridine)4(methanol)2]
  参考文献：
  名称：

  A tetracopper(II) complex of 4,6-dimethyl-2-hydroxy-isophthalic acid comprising a dimer of dinuclear subunits

  摘要：

  The dinucleating ligand 4,6-dimethyl-2-hydroxy-isophthalic acid, H3L, forms the tetracopper(II) Complex Cu4L2(O2CCH3)(2)(py)(4)(CH(3)0OH)(2) 1. The single crystal X-ray structure of 1.2CH(3)OH reveals that this complex is a carboxylate bridged dimer of dinuclear copper(II) subunits. in which the copper(II) centres adopt square-based pyramidal geometries. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2004.01.015