Zn(N-o-chlorobenzamide-meso-tetraphenylporphyrinate)Cl*CH2Cl2 | 954103-42-5

• 英文名称: Zn(N-o-chlorobenzamide-meso-tetraphenylporphyrinate)Cl*CH2Cl2
• 英文别名: Zn(N-HNCO(o-Cl)C6H4-tpp)Cl*CH2Cl2
• CAS: 954103-42-5
• 化学式: CH₂Cl₂*C₅₁H₃₃Cl₂N₅OZn
• 分子量: 953.085
• InChiKey: DXSFUVFIUCWKON-KBUNOBDBSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  盐酸 、 二氯甲烷 、 Zn(N-o-chlorobenzamidato-meso-tetraphenylporphyrinate)(MeOH)*MeOH 以 二氯甲烷 、 水 为溶剂， 以90%的产率得到Zn(N-o-chlorobenzamide-meso-tetraphenylporphyrinate)Cl*CH2Cl2
  参考文献：
  名称：

  Two-stage formation of chloro (N-o-chlorobenzamido-meso-tetraphenylporphyrinato) zinc(II) methylene chloride solvate: Zn(N-NHCO(o-Cl)C6H4-tpp)Cl·CH2Cl2

  摘要：

  The coordinating properties of N-o-chlorobenzamido-meso-tetraphenylporphyrin (N-NHCO(o-Cl)C6H4-Htpp; 11) have been investigated for the Zn2+ ion. Insertion of Zn results in the formation of the zinc complex Zn(N-NCO(o-Cl)C6H4-tpp)(MeOH)center dot MeOH (12 MeOH). The diamagnetic 12 center dot MeOH can be transformed into the diamagnetic Zn(N-NHCO(o-Cl)C6H4-tpp)Cl center dot CH2Cl2 (13 center dot CH2O2) in a reaction with aqueous hydrogen chloride (2%). X-ray structures for 12 center dot MeOH and 13 center dot CH2Cl2 have been determined. The coordination sphere around the Zn2+ ion in 12 center dot MeOH is a distorted trigonal bipyramid with N(2), N(4) and O(2) lying in the equatorial plane, whereas for the Zn2+ ion in 13 center dot CH2Cl2, it is a square-based pyramid in which the apical site is occupied by the Cl(1) atom. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.06.021