[ruthenium(II)Cl2(N-isopropylperimidine)(p-cymene)] | 864183-13-1

• 英文名称: [ruthenium(II)Cl2(N-isopropylperimidine)(p-cymene)]
• CAS: 864183-13-1
• 化学式: C₂₄H₂₈Cl₂N₂Ru
• 分子量: 516.476
• InChiKey: JJCYRJMKMSLVSF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [ruthenium(II)Cl2(N-isopropylperimidine)(p-cymene)] 、 silver trifluoromethanesulfonate 、 1,1-二苯基-2-丙炔-1-醇 以 二氯甲烷 为溶剂， 生成 [ruthenium(II)Cl(N-isopropylperimidine)(p-cymene)(CCCPh2)]triflate
  参考文献：
  名称：

  Synthesis and catalytic properties of 1-alkylperimidineruthenium(II) complexes

  摘要：

  Four new [RuCl2(perimidine)(p-cymene)] complexes have been prepared and characterized. Upon reaction with 1,1-diphenylprop-2-yn-1-ol they generate catalyst precursors. which perform the cycloisomerization of diallyltosylamide into N-tosyl-alpha-methylenepyrrolidine. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2004.12.036
• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 1-isopropylperimidine 以 噻吩 为溶剂， 以90%的产率得到[ruthenium(II)Cl2(N-isopropylperimidine)(p-cymene)]
  参考文献：
  名称：

  Synthesis and catalytic properties of 1-alkylperimidineruthenium(II) complexes

  摘要：

  Four new [RuCl2(perimidine)(p-cymene)] complexes have been prepared and characterized. Upon reaction with 1,1-diphenylprop-2-yn-1-ol they generate catalyst precursors. which perform the cycloisomerization of diallyltosylamide into N-tosyl-alpha-methylenepyrrolidine. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2004.12.036