trans-[Re(3-methyl-2-amidophenol(2-))(3-methyl-2-aminophenolato(1-))I(PPh3)2]I | 676228-85-6

• 英文名称: trans-[Re(3-methyl-2-amidophenol(2-))(3-methyl-2-aminophenolato(1-))I(PPh3)2]I
• CAS: 676228-85-6
• 化学式: C₅₀H₄₅IN₂O₂P₂Re*I
• 分子量: 1207.88
• InChiKey: XINPYWJERNNYLN-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-氨基-3-甲基苯酚 、 iododioxobis(triphenylphosphine)rhenium(V) 以 乙醇 为溶剂， 以47%的产率得到trans-[Re(3-methyl-2-amidophenol(2-))(3-methyl-2-aminophenolato(1-))I(PPh3)2]I
  参考文献：
  名称：

  The reaction of the cis-dioxorhenium(V) core with N,O-donor ligands: mono and bidentate coordination of 3-methyl-2-aminophenol

  摘要：

  The reaction of cis-[ReO2I(PPh3)(2)] with 3-methyl-2-aminophenol (H(2)map) in ethanol led to the formation of traps-[Re (map)(Hmap)I(PPh3)(2)]I. The X-ray crystal structure shows that the ligand map is coordinated monodentately through the doubly deprotonated amino nitrogen and is therefore present as an imide. The chelate Hmap is coordinated via the neutral amino nitrogen and the singly deprotonated phenolate oxygen, which is coordinated trans to the imido nitrogen. In benzene equimolar quantities of cis-[ReO2I(PPh3)(2)] and 4-methyl-2-aminophenol (H(2)amp) produced the five-coordinate cis-[ReO2(Hamp)(PPh3)]. A twofold molar excess of 2-aminophenol (H(2)ap) yielded the six-coordinate [ReO(Hap)(ap)(PPh3)]. The chelate ap is coordinated through the deprotonated phenolate oxygen and the singly deprotonated amino nitrogen (amide). (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.06.010