| 767334-56-5

• CAS: 767334-56-5
• 化学式: C₄₂H₄₆FeNOPPd
• 分子量: 774.074
• InChiKey: YPWXKPTVMQOOAJ-FYKVSQGXSA-N

反应信息

• 作为反应物：
  描述：

  tris(dibenzylideneacetone)dipalladium (0) 、 以 氘代苯 为溶剂， 生成 [(((CH₃)3C)2PC₅H₄FeC₅H₄CHNC₆H₅)2Pd]
  参考文献：
  名称：

  Efficient Suzuki Coupling of Aryl Chlorides Catalyzed by Palladium(0) with a P,N Heteroligand and Isolation of Unsaturated Intermediates

  摘要：

  A mixture of Pd-2(dba)(3) / [eta-C5H4CH=N(C6H5)]-Fe[eta-C5H4P(t-Bu)(2)] (1) efficiently catalyzes the Suzuki cross-couplings of a range of arylboronic acids and aryl chlorides, affording the desired biaryl products in high isolated yields. Two catalytically active Pd(0) intermediates, viz. 16-electron [eta-C5H4CH=N(C6H5)]Fe[eta-C5H4P(t-Bu)(2)]Pd(dba) (2) and 14-electron linear Pd{[eta-C5H4CH=N(C6H5)]Fe[eta-C5H4P(t-BU)(2)]}(2) (3) together with an oxidative addition product are isolated and crystallographically established.

  DOI：

  10.1021/om0494770
• 作为产物：
  描述：

  tris(dibenzylideneacetone)dipalladium (0) 、 [[η-C5H4CH=N(C6H5)]Fe[η-C5H4P(tBu)2]] 以 氘代苯 为溶剂， 生成 、 [(((CH₃)3C)2PC₅H₄FeC₅H₄CHNC₆H₅)2Pd]
  参考文献：
  名称：

  Efficient Suzuki Coupling of Aryl Chlorides Catalyzed by Palladium(0) with a P,N Heteroligand and Isolation of Unsaturated Intermediates

  摘要：

  A mixture of Pd-2(dba)(3) / [eta-C5H4CH=N(C6H5)]-Fe[eta-C5H4P(t-Bu)(2)] (1) efficiently catalyzes the Suzuki cross-couplings of a range of arylboronic acids and aryl chlorides, affording the desired biaryl products in high isolated yields. Two catalytically active Pd(0) intermediates, viz. 16-electron [eta-C5H4CH=N(C6H5)]Fe[eta-C5H4P(t-Bu)(2)]Pd(dba) (2) and 14-electron linear Pd{[eta-C5H4CH=N(C6H5)]Fe[eta-C5H4P(t-BU)(2)]}(2) (3) together with an oxidative addition product are isolated and crystallographically established.

  DOI：

  10.1021/om0494770