| 138957-27-4

• CAS: 138957-27-4；150407-75-3
• 化学式: C₁₅H₇NO₁₁Os₃
• 分子量: 947.821
• InChiKey: WDIYTDHQKNMEJB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 乙腈 在 Me₃NO 作用下， 以 二氯甲烷 、 乙腈 为溶剂， 以76%的产率得到
  参考文献：
  名称：

  Os3（CO）10（CNR）（NCMe）的合成及其与丙酸的反应

  摘要：

  The nitrile derivatives Os3(CO)10(CNR)(NCMe) (2) have been prepared by the reaction of isocyanide complexes Os3(CO)11(CNR) (1) with Me3NO in the presence of CH3CN. The labile complex 2 on reaction with two-electron donor ligands L (L = CO, PPh3, PMePh2) gives Os3(CO)10(CNR)L (3). Treatment of 2 with propynoic acid (HC=CCO2H) in CH2Cl2 yields the hydrido complexes (mu-H)Os3(CO)10(mu2-OCOC=CH)(CNR) (4); however, complex 2 reacts with propynoic acid in acetonitrile to form complex 4 and the bridging aminocarbyne species Os3(CO)10(mu2-OCOC=CH)(mu2-C=NHR) (5) containing a unique bridging unidentate (mu2-eta1-oxo) carboxylate ligand. Molecular structures of Os3(CO)10(CNPr)(PPh3)(3a) and Os3(CO)10(mu2-OCOC=CH)(mu2-C=NHPr) (5a) have been determined by X-ray diffraction studies. Crystal data are as follows. 3a: P1BAR; a = 11.4611 (14), b = 11.6963 (19), c = 14.9661 (22) angstrom; a = 93.635 (12), beta = 73.633 (11), gamma = 117.325 (11)-degrees; V = 1705.0 (4) angstrom3, Z = 2; R = 4.2%, R(w) = 5.1%. 5a: P2(1)2(1)2(1); a = 9.4241 (23), b = 15.414 (4), c = 15.972 (3) angstrom; V = 2320.2 (9) angstrom3, Z = 4; R = 3.2%, R(w) = 3.5%.

  DOI：

  10.1021/om00059a055
• 作为产物：
  描述：

  十二羰基三锇 、 N-(Triphenylphosphoranylidene)isopropylamine 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  cluster簇配位域中异氰酸酯配体的转化。iso异氰化物络合物与胺的反应

  摘要：

  The osmium isocyanide complexes Os3-(CO)11(CNR) (1), synthesized from Os3(CO)12 and phosphine imides (Ph3P = NR), react with primary amines to afford the carboxamido complexes Os3(CO)10(mu(2)-CONHR')(mu(2)-C = NHR) (2) with a bridging aminocarbyne. The latter react with excess corresponding amines to yield Os3(CO)9(NH2R')(mu(2)-CONHR')(mu(2)-C = NHR) (3), which when passed through silica gel transform to produce the hydrido complexes (mu-H)Os3(CO)9(mu(2)-CONHR')(CNR) (4) with the regeneration of the isocyanide ligand. The transformation of the isocyanide ligand with the cleavage and formation of an Os-Os bond may play an important role in mediating the reactivity of the osmium cluster.

  DOI：

  10.1021/om00040a008

文献信息

• Lu, Kuang-Lieh; Chen, Chi-Cheng; Lin, Yen-Wen, Journal of Organometallic Chemistry, 1993, vol. 453, p. 263 - 268
  作者：Lu, Kuang-Lieh、Chen, Chi-Cheng、Lin, Yen-Wen、Hong, Fung-E.、Gau, Han-Mou、et al.

  DOI：——

  日期：——
• Effect of isocyanide ligand on the interaction of triosmium isocyanide complexes with amines
  作者：Kuang Lieh Lu、Chi Jen Chen、Yen Wen Lin、Han Mou Gau、Fung E. Hong、Yuh Sheng Wen

  DOI：10.1021/om00030a031

  日期：1993.6

  The interaction of the osmium isocyanide complexes Os3(CO)11(CNR) (1) with primary amines leads initially to the formation of the carboxamido complexes Os3(CO)10(mu2-CONHR')(mu2-C=NHR) (2) with a bridging aminocarbyne. The latter react with excess corresponding amines to yield Os3(CO)9(NH2R')(mu2-CONHR')(mu2-C=NHR) (3). Bubbling CO through the solution of 3 regenerates 2. Treatment of complex 2 with PPh3 affords Os3(CO)9(PPh3)(mu2-CONHR')(mu2-C=NHR) (5). Complex 3, when passed through silica gel, results in structure transformation to the hydrido complexes (mu-H)Os3(CO)9(mu2-CONHR')(CNR) (4) with the regeneration of the isocyanide ligand. Treatment of 3 with CH3CO2H or CF3CO2H also results in the formation of 4. In contrast, complex 2 or complex 5 remains unchanged when passed through silica gel. The transformation of the isocyanide ligand with the cleavage and formation of an Os-Os bond may play an important role in mediating the reactivity of the osmium cluster. The structures of Os3(CO)10(mu2-CONHPr(i))(mu2-C=NHCH2Ph) (2c), Os3(CO)9(NH2Pr(i))(mu2-CONHPr(i))(mu2-C=NBPh) (3a), and (mu-H)Os3(CO)9(mu2-CONHPr(i))(CNCH2Ph) (4c) have been determined by X-ray crystallography. Crystal data are as follows. 2c: Pbca; a = 11.9975(14) angstrom, b = 17.797(4) angstrom, c = 25.819(3) angstrom; V = 5512.9(14) angstrom3, Z = 8; R = 5.6%, R(w) = 5.9%. 3a: P1BAR; a = 8.7042(13) angstrom, b = 13.1002(20) angstrom, c = 13.546(4) angstrom, alpha = 93.456(17)-degrees; beta = 89.905(16)-degrees, gamma = 106.393(13)-degrees; V = 1478.9(5) angstrom3, z = 2; R = 3.8%, R(w) = 4.5%. 4c: P2(1)/n; a = 9.3811(15) angstrom, b = 10.0523(14) angstrom, c 28.265(17) angstrom; beta = 91.81(3)-degrees; V = 2664.1(17) angstrom3, z = 4; R = 3.6%, R(w) = 4.2%.