[C6H4-1,3-(OPPh2(Ru(η6-p-cymene)Cl2))2] | 914806-29-4

• 英文名称: [C6H4-1,3-(OPPh2(Ru(η6-p-cymene)Cl2))2]
• CAS: 914806-29-4
• 化学式: C₅₀H₅₂Cl₄O₂P₂Ru₂
• 分子量: 1090.86
• InChiKey: MKIABWLZFRMEMX-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 resorcinolbis(diphenyl)phosphinite 以 二氯甲烷 为溶剂， 以56%的产率得到[C6H4-1,3-(OPPh2(Ru(η6-p-cymene)Cl2))2]
  参考文献：
  名称：

  Ketone transfer hydrogenation reactions catalyzed by a phosphinite ruthenium PCP complex

  摘要：

  The reaction of the potentially tridentate phosphinite PCP pincer type ligand [C6H4-1,3-(OPPh2)(2)] with [eta(6)-p-cymene)RuCl2](2) affords the bimetallic species [C6H4-1,3-(OPPh2{Ru(eta(6)-p-cymene)Cl-2})(2)]. Several attempts, including the change of the ruthenium starting material (e.g. [(eta(6) -benzene)RuCl2](2)) and reflux conditions to achieve the coordination of the diphosphinite [C6H4-1,3-(OPPh2)(2)] in a tridentate PCP pincer fashion failed. Complex [C6H4-1,3-(OPPh2{Ru(eta(6)-p-cymene)Cl-2})(2)] was tested in the transfer hydrogenation of ketones. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2005.11.041