[Co3(μ3-CC(O)OCH2CHCH2)(CO)7(triphenylphosphane)2] | 725713-45-1

• 英文名称: [Co3(μ3-CC(O)OCH2CHCH2)(CO)7(triphenylphosphane)2]
• CAS: 725713-45-1
• 化学式: C₄₈H₃₅Co₃O₉P₂
• 分子量: 994.728
• InChiKey: URIZISCKWLKCCH-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  Co3(μ3-CC(O)OCH2CHCH2)(CO)9 、 三苯基膦 以 二氯甲烷 为溶剂， 以17%的产率得到[Co3(μ3-CC(O)OCH2CHCH2)(CO)7(triphenylphosphane)2]
  参考文献：
  名称：

  Synthesis and characterisation of phosphane-substituted Co3C clusters having a pendant allyl side-chain

  摘要：

  Substituted mu(3)-carbido-capped tricobalt carbonyl clusters have been synthesised by reaction of [CO3(mu(3)-C(O)OCH2CH=CH2)(CO)(9)] with a range of monodentate and chelating phosphane ligands. The products have been characterised by microanalysis, IR and NMR spectroscopy, mass spectrometry and, in the case of [CO3(mu(3)-CR)(CO)(7)(dppe)], [Co-3(mu(3)-CR)(CO)(7)(dppm)], [Co-3(mu(3)-CR)(CO)(7)(PPh3)(2)], [Co-3(mu(3)-CR)(CO)(7)(PMe3)(2)] and [Co-3(mu(3)-CR)(CO)(6)(PEt3)(3)] (R=C(O)OCH2CH=CH2), single crystal X-ray diffraction. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.03.036