| 216980-01-7

• CAS: 216980-01-7
• 化学式: C₃₀H₂₀N₄Ni₂O₃S
• 分子量: 633.96
• InChiKey: AMUJMTYAZAHLRM-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1-N,3-N-bis(2-aminophenyl)-2-hydroxy-5-methylbenzene-1,3-dicarboxamide 、 nickel(II) perchlorate 、 S-(2,6-diformyl-4-methylphenyl) dimethylthiocarbamate 在 sodium hydroxide 作用下， 以 异丙醇 为溶剂， 以78%的产率得到
  参考文献：
  名称：

  Binuclear nickel(II) and copper(II) complexes of amide-containing two-armed and macrocyclic ligands

  摘要：

  Two new acyclic, potentially binucleating amide-containing ligands, H(3)L1 and H(3)L2, have been synthesised from the reaction of 4-methylphenol-2,6-diacyl chloride with an excess of 1,2-diaminobenzene or of 1,2-diamino-4,5-dimethylbenzene, respectively. Dicopper(II) complexes, [Cu-2(L1)(X)] where X = CH3COO- or OH-, have been made from H(3)L1 but the analogous nickel complexes could not be prepared and no complexes with either copper or nickel could be prepared from H(3)L2. Interestingly, Schiff-base macrocyclic complexes derived from reactions of H(3)L1 and H(3)L2 with 2,6-diformyl-4-methylphenol, 4-t-butyl-2,6-diformylphenol, or S-(2,6-diformyl-3-methylphenyl) -dimethylthiocarbamate, were successfully templated using these same two metal ions and resulted in the isolation of nine dimetallic complexes. A variety of structural modifications were made to the macrocycles via the choice of dialdehyde precursor, including changing a phenolate bridge for a thiophenolate one, in an attempt to increase the solubility of the products. (C) 1998 Elsevier Science S.A, All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00240-0