[(N-methyl-[bis(2-pyridyl)methyl]amine)CuCl2] | 1005386-88-8

• 英文名称: [(N-methyl-[bis(2-pyridyl)methyl]amine)CuCl2]
• 英文别名: [(Me-bpa)CuCl2]
• CAS: 1005386-88-8；1030833-85-2
• 化学式: C₁₃H₁₅Cl₂CuN₃
• 分子量: 347.734
• InChiKey: ZXDXPPHMVBCGLF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 N-methyl-N,N-di(2-pyridylmethyl)amine 以 甲醇 为溶剂， 以79%的产率得到[(N-methyl-[bis(2-pyridyl)methyl]amine)CuCl2]
  参考文献：
  名称：

  Syntheses, characterization, and reactivity of copper complexes with tridentate N-donor ligands

  摘要：

  The reaction of dioxygen with the copper(I) complex of the tridentate ligand 1,1,4,7,7-pentamethyldiethylenetriamine (Me(5)dien) has been investigated using low-temperature stopped-flow techniques. The formation of a bis( mu-oxo)copper(III) complex as a reactive intermediate could be detected spectroscopically at low temperatures and a quantitative kinetic analysis was performed for this system. Crystal structures of the copper(II) complexes [(Me-bpa)Cu(Cl)(2)] (1), [{(Me-bpa)Cu(Cl)(ClO4)}(2)] (2), [{(MeL)Cu(Cl)(ClO4)}(2)] (3), and [(MeL)Cu(NCS)(2)] (4) (Me-bpa=N-methyl-[bis(2-pyridyl)methyl]amine; MeL=N-methyl-[(2-pyridyl)ethyl(2-pyridyl)methyl]amine) are reported. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.07.018