[(η(5)-CH3OCC5H4)2Mo2(CO)4] | 148534-90-1

• 英文名称: [(η(5)-CH3OCC5H4)2Mo2(CO)4]
• 英文别名: [(η(5)-MeCOC5H4)Mo(CO)2]2；(η5-MeCOC5H4Mo)2；(η(5)-MeCOC5H4)2Mo2(CO)4
• CAS: 148534-90-1
• 化学式: C₁₈H₁₄Mo₂O₆
• 分子量: 518.186
• InChiKey: ROPUBXQZLHOUTL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(η(5)-CH3OCC5H4)2Mo2(CO)4] 、 二苯基二硒醚 以 甲苯 为溶剂， 生成 (CH₃COC₅H₄)2Mo₂(CO)2(C₆H₅)2Se₂
  参考文献：
  名称：

  Song, Li-Cheng; Shi, Yao-Cheng; Hu, Qing-Mei, Polyhedron, 1999, vol. 18, p. 19 - 24

  摘要：

  DOI：

文献信息

• Reactions of metal–metal triply bonded complexes [(η5-RC5H4)2M2(CO)4] (M=Mo, W) with diphenyl ditelluride. Crystal structures of [(η5-MeC5H4)Mo2(CO)4(μ-TePh)3] and [(η5-EtO2CC5H4)2W2(CO)4(μ-TePh)2]
  作者：Li-Cheng Song、Yao-Cheng Shi、Qing-Mei Hu、Yu Chen、Jie Sun

  DOI：10.1016/s0022-328x(01)00695-7

  日期：2001.4

  [(η5-RC5H4)2M2(CO)4] with Ph2Te2 in solution and solid state were investigated. While [(η5-RC5H4)2M2(CO)4] (M=Mo, R=H, Me3Si, MeCO; M=W, R=MeCO, MeO2C, EtO2C) reacted with Ph2Te2 in toluene at reflux to give a series of doubly bridged complexes [(η5-RC5H4)2M2(CO)4(μ-TePh)2] (1, M=Mo, R=H; 2, Mo, Me3Si; 3, Mo, MeCO; 4, W, MeCO; 5, W, MeO2C; 6, W, EtO2C), the reaction of [(η5-MeC5H4)2Mo2(CO)4] with Ph2Te2

  三重接合复合物的反应[（η 5 -RC 5 H ^ 4）2中号2（CO）4 ]的Ph 2碲2在溶液和固体状态进行了调查。虽然[（η 5 -RC 5 H ^ 4）2中号2（CO）4 ]（M =钼，R = H中，Me 3的Si，梅科; M = W，R =梅科，的MeO 2 C，环氧乙烷2 C）的Ph反应2碲2在甲苯中在回流下，得到了一系列双桥联配合物[（η 5 -RC 5 H ^4）2 M 2（CO）4（μ-TePh）2 ]（1，M = Mo，R = H; 2，Mo，Me 3 Si; 3，Mo，MeCO; 4，W，MeCO; 5，W ，的MeO 2 C。; 6，W，环氧乙烷2 C），的反应[（η 5 -MeC 5 ħ 4）2的Mo 2（CO）4 ]的Ph 2碲2在相同条件下产生的，不仅双对应桥连的络合物[（η 5 -MeC 5ħ 4）2的Mo 2（CO）4（μ-TePh）2 ]（7），而且还意外三重桥接络合物[（η
• Synthesis of the Novel Thiolato-Bridged and Oxo-Capped Trimetallic Clusters (η⁵-R‘C₅H₄)(CO)₂MFe₂(μ₃-O)- (μ-RS)(CO)₆ via Reactions of [Et₃NH][(μ-RS)(μ-CO)- Fe₂(CO)₆] with Triply Bonded Dimers [(η⁵-R‘C₅H₄)(CO)₂M]₂ (M = Mo, W) and Subsequent Treatment with Air. Crystal Structures of (η⁵-MeO₂CC₅H₄)(CO)₂MoFe₂(μ₃-O)(μ-<i>t</i>-BuS)(CO)₆ and (η⁵-EtO₂CC₅H₄)(CO)₂WFe₂(μ₃-O)(μ-EtS)(CO)₆
  作者：Li-Cheng Song、Hong-Tao Fan、Qing-Mei Hu、Xiang-Dong Qin、Wen-Feng Zhu、Yu Chen、Jie Sun

  DOI：10.1021/om980035w

  日期：1998.8.1

  [Et3NH][(μ-RS)(μ-CO)Fe2(CO)6] (1:  R = Et, t-Bu, Ph), prepared from Fe3(CO)12, RSH, and Et3N, react in situ with the triply bonded dimers [(η5-R‘C5H4)(CO)2M]2 (2:  M = Mo, W; R‘ = H, MeCO, MeO2C, EtO2C) followed by treatment with air to give the series of novel clusters (η5-R‘C5H4)(CO)2MoFe2(μ3-O)(μ-RS)(CO)6 (compound, R, R‘:  3a, Et, H; 3b, t-Bu, H; 3c, Et, MeCO; 3d, t-Bu, MeO2C; 3e, Ph, MeO2C; 3f, Et, EtO2C; 3g, t-Bu

  由Fe 3（CO）12，RSH制备的络合盐[Et 3 NH] [（μ-RS）（μ-CO）Fe 2（CO）6 ]（1：R = Et，t -Bu，Ph），和Et 3 N，在原位反应与三重接合二聚体[（η 5 -R'C 5 ħ 4）（CO）2 M] 2（2：M =钼，钨; R” = H，梅科，的MeO 2 C，环氧乙烷2 C），接着用空气处理，得到一系列新的簇的（η 5 -R'C 5 ħ 4）（CO）2钼铁2（μ 3 -O）（μ-RS）（CO）6（化合物中，R，R'：  3a中，ET，H;图3b，吨-Bu，H; 3c中，ET，梅科; 3D，吨-Bu，的MeO 2 ℃;图3e中，Ph，的MeO 2 C。; 3F，ET，环氧乙烷2 ℃; 3克，吨-Bu，环氧乙烷2 ℃; 3H，pH值，环氧乙烷2 C）在26-37％的产率和（η 5 -R” ç 5 ħ 4）（CO）2 WFE 2（μ 3 -O）（μ-RS）（CO）6（化合物，R，R'：
• Synthesis and characterization of sulfur/iron/molybdenum (tungsten) cluster compounds containing functionally substituted cyclopentadienyl ligand. Single crystal structure of [(ν5-MeO2CC5H4)2 (μ3-CO)2Mo2Fe2(μ3-S)2(CO6]
  作者：Li-Cheng Song、Ji-Quan Wang、Qing-Mei Hu、Wen-Qi Gao、Bing-Song Han

  DOI：10.1016/0277-5387(96)00285-9

  日期：1997.1

  [ν5-RC5H4(CO)2Mo]2 in CH2Cl2 at room temperature gave clusters [η5-RC5H4)2(μ3-CO)2Mo2Fe2(μ3-S)2(CO)6] (1a, R=MeCO; 1b, R = MeO2C; 1 c , R = EtO 2 C , whereas μ-S2Fe2(CO)6 reacted with WW triply bonded dimers [ν5-RC5H4(CO)2W]2 to afford the clusters [(ν5-RC5H4)2(μ3-CO)2W2Fe2(μ3-S)2(CO)6] (2a, R = MeO2C; 2b, R = EtO2C) and [[η5-RC5H4(CO)2]2W2Fe(μ3-S)(CO)3] (3a, R = MeO2C; 3b, R = EtO2C). While clusters 1a–1c could

  团簇1a在室温下与NaBH4在MeOH中的反应生成双羟基衍生物[[ν5-MeCH（OH）C5H4] 2（μ3-CO）2Mo2Fe2（μ3-S）2（CO）6]（4），而得到了单hydr和双-衍生物[ν5-MeCOC5H4] [ν5-2,4-（NO2）2C6H3NHNC（Me）C5H4]（μ3-CO）2Mo2Fe2（μ3-S）2（CO）6]（5）与[[ν5-2,4-（ ）2C6H3H | NHNC（Me）C55H4] 2（μ3-CO）2Fe2（μ3-S）2（CO）6]（6）与2,4-二硝基苯肼在室温下加入乙醇。所有新的团簇都通过元素分析和光谱学方法进行了表征，并通过X射线衍射技术对1b进行了表征。
• Preparation of (η5-RC5H4)2Mo2(CO)2(μ-PhS)2 (R=H, MeCO) by the reaction of [η5-RC5H4Mo(CO)2]2 with (μ-PhS)2Fe2(CO)6. Crystal structures and acetyl transformation reactions of two isomers trans/anti- and trans/syn-(η5-MeCOC5H4)2Mo2(CO)2(μ-PhS)2
  作者：Li-Cheng Song、Ji-Quan Wang、Qing-Mei Hu、Ru-Ji Wang、Thomas C.W. Mak

  DOI：10.1016/s0020-1693(96)05412-6

  日期：1997.3

  triply bonded complexes [η 5 -RC 5 H 4 Mo(CO) 2 ] 2 with the Fe/S butterfly compound (μ-PhS) 2 Fe 2 (CO) 6 in refluxing xylene gives two corresponding MoMo doubly bonded complexes (η 5 -RC 5 H 4 ) 2 Mo 2 (CO) 2 (μ-PhS) 2 . Each of the complexes consists of two isomers, namely trans/anti and trans/syn , in terms of the relative arrangement of the RC 5 H 4 and CO ligands and the mutual orientation of

  MoMo三键结合的配合物[η5 -RC 5 H 4 Mo（CO）2] 2与Fe / S蝶形化合物（μ-PhS）2 Fe 2（CO）6在回流的二甲苯中反应得到两个相应的Mo Mo双键络合物（η5 -RC 5 H 4）2 Mo 2（CO）2（μ-PhS）2。就RC 5 H 4和CO配体的相对排列以及桥联硫原子上苯基的相互取向而言，每种络合物均由两个异构体组成，即反式/反式和反式/顺式。具有R ＝ MeCO的两种异构体在回流下可在二甲苯中彼此转化，并且已经通过X射线衍射在晶体学上确定。R = MeCO络合物与NaBH 4和MeMgI的进一步反应得到两种相应的官能羟基衍生物[η5 -MeCH（OH）C 5 H 4] 2 Mo 2（CO）2（μ-PhS）2和[η5- Me 2 C（OH）C 5 H 4] 2 Mo 2（CO）2（μ-PhS）2。
• Investigations on Novel Tandem Reaction of Three Components, [η⁵-RC₅H₄(CO)₂Mo]₂, Ph₂Te₂, and Cp₂TiCl₂, Cp₂ZrCl₂, or Cp₂ZrBr₂. Synthesis and Structural Characterization of Tetrakis- and Bis-Bridged Dimolybdenum Complexes (η⁵-RC₅H₄Mo)₂(μ-PhTe)₄ (R = MeCO, MeO₂C, EtO₂C), (η⁵-RC₅H₄Mo)₂(μ-Cl)(μ-PhTe)₃ (R = MeCO, MeO₂C, EtO₂C), (η⁵-RC₅H₄Mo)₂(μ-Br)(μ-PhTe)₃ (R = MeO₂C, EtO₂C), and [η⁵-RC₅H₄(CO)₂Mo]₂(μ-PhTe)₂ (R = MeO₂C, EtO₂C)
  作者：Li-Cheng Song、Yao-Cheng Shi、Wen-Feng Zhu、Qing-Mei Hu、Xiao-Ying Huang、Fei Du、Xi-An Mao

  DOI：10.1021/om9904448

  日期：2000.1.1

  While reaction of triply bonded dimers [eta(5)-RC5H4(CO)(2)Mo](2) (R = MeCO, MeO2C) with Ph-2-Te-2 in xylene at 110 degrees C and subsequent treatment with Cp2TiCl2 at reflux gives novel tetrakis-bridged complexes (eta(5)-RC5H4Mo)(2)(mu-PhTe)(4) (1, R = MeCO; 3, R = MeO2C) and (eta(5)-RC5H4Mo)(2)(mu-Cl)(mu-PhTe)(3) (2a,b, R = MeCO; 4a,b, R = MeO2C), the dimers [eta(5)-RC5H4(CO)(2)Mo](2) (R = MeO2C, EtO2C) reacted with Ph2Te2 and Cp2ZrCl2 or Cp2ZrBr2 under similar conditions to afford novel tetrakis-bridged complexes (eta(5)-RC5H4Mo)(2)(mu-PhTe)(4) (3, R = MeO2C; 5, R = EtO2C), (eta(5)-RC5H4Mo)(2)(mu-Cl)(mu-PhTe)(3) (4a,b, R = MeO2C; 6a,b, R = EtO2C), and (eta(5)-RC5H4Mo)(2)(mu-Br)(mu-PhTe)(3) (7a,b, R = MeO2C; 8a,b, R = EtO2C). A possible pathway for production of such tetrakis-bridged complexes has been suggested primarily on the basis of the following facts: (i) Treatment of triply bonded dimers [eta(5)-RC5H4(CO)(2)Mo](2) (R = MeO2C, EtO2C) with Ph2Te2 in xylene at 110 degrees C produces bis-bridged complexes [eta(5)-RC5H4(CO)(2)Mo](2)(mu-PhTe)(2) (9, R = MeO2C; 10, R = EtO2C) and (ii) reaction of 9 with Cp2MCl2 (M = Ti, Zr) yields tetrakis-bridged complexes 3 and 4a,b. All the new products 1-10 are fully characterized by elemental analysis and IR, H-1, and Te-125 NMR spectroscopies, and 4b and 9 by single-crystal X-ray diffraction techniques.