[Fe(κ2-dppe)2(NCMe)2][(μ-dppe)(FeCl3)2] | 185611-45-4

• 英文名称: [Fe(κ2-dppe)2(NCMe)2][(μ-dppe)(FeCl3)2]
• CAS: 185611-45-4
• 化学式: C₂₆H₂₄Cl₆Fe₂P₂*C₅₆H₅₄FeN₂P₄
• 分子量: 1657.64
• InChiKey: AVQJRRSWUOVCLH-UHFFFAOYSA-H

反应信息

• 作为产物：
  描述：

  1,2-双(二苯基膦)乙烷 、 iron(II) chloride 在 sodium 2-mercaptobenzothioazolate 、 actonitrile 作用下， 以 二氯甲烷 、 乙腈 为溶剂， 以25%的产率得到[Fe(κ2-dppe)2(NCMe)2][(μ-dppe)(FeCl3)2]
  参考文献：
  名称：

  Mixed Coordination Modes of 1,2-bis(Diphenylphosphino)Ethane in the Ionic Triiron(II) Complex [Fe(dppe)₂(MeCN)₂][(FeCl₃)₂(μ₂-dppe)]

  摘要：

  The iron(II) complex salt [Fe(dppe)(2)(MeCN)(2)][(FeCl3)(2)(mu 2-dppe)] (1) was synthesized by the reaction of FeCl2 with dppe in the presence of sodium 2-mercaptobenzothiazole(Nambt). The molecule contains a mononuclear Fe(II) cation and a binuclear Fe(II) anion with the three dppe ligands in two coordination modes. A single crystal x-ray study showed that the anionic part has a zigzagging chain of a Fe2P2C2 core without metal-metal bonding but having an eta(1),eta(1)-dppe bridge between two trans-oriented FeCl3 moieties with Fe(II) in tetrahedral geometry. The cation has two dppe ligands in the equatorial and two acetonitrile molecules in the axial positions forming an octahedral coordination environment for iron.

  DOI：

  10.1080/00945719608004398

文献信息

• p-Diethynylbenzene-based molecular wires, Fe–C C-p-C6H2X2–C C–Fe [Fe= Fe(η5-C5Me5)(dppe)]: Synthesis, substituent effects and unexpected formation of benzodifuran complex
  作者：Yumi Matsuura、Yuya Tanaka、Munetaka Akita

  DOI：10.1016/j.jorganchem.2009.01.019

  日期：2009.5

  A series of p-diethynylbenzene- based molecular wires, Fe-C C-p-C6H2X2-C C-Fe (3) (Fe = FeCp* (dppe)), is prepared and their wire-like performance is estimated on the basis of the K-C and V-ab values. It has been revealed that electron-donating substituents (X) improve the performance. The benzodifuran complex 4 unexpectedly formed from the derivative with X = OH shows the performance comparable to 3. (C) 2009 Elsevier B.V. All rights reserved.