[Co(4'-(4'''-pyridyl)-2,2':6',2''-terpyridine)Cl2]*CH3OH | 736928-76-0

• 英文名称: [Co(4'-(4'''-pyridyl)-2,2':6',2''-terpyridine)Cl2]*CH3OH
• CAS: 736928-76-0
• 化学式: CH₄O*C₂₀H₁₄Cl₂CoN₄
• 分子量: 472.299
• InChiKey: BMSJGMRNXFSOTN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Co(4'-(4'''-pyridyl)-2,2':6',2''-terpyridine)Cl2]*CH3OH 、 水 以 neat (no solvent) 为溶剂， 生成 [Co(4'-(4'''-pyridyl)-2,2':6',2''-terpyridine)Cl2]*2H2O
  参考文献：
  名称：

  1-D Cobalt(II) Spin Transition Compound with Strong Interchain Interaction:  [Co(pyterpy)Cl₂]·X

  摘要：

  Cobalt(II) compounds [Co(pyterpy)Cl-2].MeOH (1.(MeOH)) and [Co(pyterpy)Cl-2].2H(2)O (1.(2H(2)O)) were synthesized. The compound 1.(MeOH) forms the quasi 3-D networks by making pi-pi stacking between the 1-D chains. The methanol molecules from 1.(MeOH) can be removed by heating, and substituted by absorption of water molecules. The MeOH molecules in 1.(MeOH) are removed by heating at 410 K, and they are substituted by water molecules to form 1.(2H(2)O). 1.(2H(2)O) exhibits a S = 3/2 (HS) reversible arrow S = 1/2 (LS) spin transition with a thermal hysteresis. We have succeeded in constructing a guest dependent 1-D spin-crossover cobalt(II) compound.

  DOI：

  10.1021/ic049509b
• 作为产物：
  描述：

  甲醇 、 cobalt(II) chloride hexahydrate 、 4'-(4-吡啶基)-2,2':6',2''-三联吡啶 以 甲醇 为溶剂， 生成 [Co(4'-(4'''-pyridyl)-2,2':6',2''-terpyridine)Cl2]*CH3OH
  参考文献：
  名称：

  1-D Cobalt(II) Spin Transition Compound with Strong Interchain Interaction:  [Co(pyterpy)Cl₂]·X

  摘要：

  Cobalt(II) compounds [Co(pyterpy)Cl-2].MeOH (1.(MeOH)) and [Co(pyterpy)Cl-2].2H(2)O (1.(2H(2)O)) were synthesized. The compound 1.(MeOH) forms the quasi 3-D networks by making pi-pi stacking between the 1-D chains. The methanol molecules from 1.(MeOH) can be removed by heating, and substituted by absorption of water molecules. The MeOH molecules in 1.(MeOH) are removed by heating at 410 K, and they are substituted by water molecules to form 1.(2H(2)O). 1.(2H(2)O) exhibits a S = 3/2 (HS) reversible arrow S = 1/2 (LS) spin transition with a thermal hysteresis. We have succeeded in constructing a guest dependent 1-D spin-crossover cobalt(II) compound.

  DOI：

  10.1021/ic049509b