InCl3*3H2O*18-crown-6 | 135559-84-1

• 英文名称: InCl3*3H2O*18-crown-6
• 英文别名: mer-InCl3(H2O)*18C6
• CAS: 135559-84-1
• 化学式: C₁₂H₂₄O₆*Cl₃H₆InO₃
• 分子量: 539.544
• InChiKey: OTDWJIXPOYKBDT-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  18-冠醚-6 、 indium(III)trichloride tetrahydrate 以 乙腈 为溶剂， 生成 InCl3*3H2O*18-crown-6
  参考文献：
  名称：

  Strel'tsova, N. R.; Ivanov, M. G.; Vashchenko, S. D., Koordinatsionnaya Khimiya, 1991, vol. 17, p. 354 - 358

  摘要：

  DOI：

文献信息

• Isomerization of [In(H2O)3Cl3] · 18C6. Crystal structure of [mer-In(H2O)3Cl3] · 18C6 and [fac-In(H2O)3Cl3] · 18C6 · 2H2O
  作者：A. B. Ilykhin、Zh. V. Dobrokhotova、S. P. Petrosyants

  DOI：10.1134/s1070328408090029

  日期：2008.9

  The complex [mer-In(H2O)(3)Cl-3] center dot 18C6 (I) was isolated from the InCl3-H2O-Solv-18C6 solutions (Solv = MeOH, EtOH, THF). The second crystallization from mother solutions resulted in [fac-In(H2O)(3)Cl-3] center dot 18C6 center dot 2H(2)O (II). The crystal and molecular structures of isomers I, II were identified by the powder X-ray diffraction, IR, and X-ray diffraction methods. Although complexes I, II have different compositions, they have the chain structure. The thermal decomposition of complexes I, II was studied.