| 343313-77-9

• CAS: 343313-77-9
• 化学式: C₆₅H₅₅Cl₂N₇Pd₂
• 分子量: 1217.94
• InChiKey: HDCIEJSUHLWKGA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 以 N,N-二甲基甲酰胺-d7 为溶剂， 生成
  参考文献：
  名称：

  Supramolecular Recognition Forces:  An Examination of Weak Metal−Metal Interactions in Host−Guest Formation

  摘要：

  Molecular receptors consisting of two parallel-disposed terpy-M-Cl units (M = Pd2+, Pt2+) are used to form host-guest adducts with aromatic molecules and with neutral square-planar Pt2+ complexes. Host-guest formation is controlled by several factors including pi-pi interactions and, in some cases, weak Pt-Pt interactions between the host and the guest. This latter interaction was examined by comparing the host-guest stability of adducts formed by isoelectronic Pt2- and Au3+ complexes with the Pt2+ receptor. Consistently, the former is more stable.

  DOI：

  10.1021/ic0481531