| 1055212-26-4

• CAS: 1055212-26-4
• 化学式: C₂₂H₃₆PRhS
• 分子量: 466.473
• InChiKey: GXOWLKGOXFWMBP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 not given 为溶剂， 生成
  参考文献：
  名称：

  Bond cleavage reactions in substituted thiophenes by a rhodium complex

  摘要：

  The reactions of (C(5)Me(5)) Rh(PMe(3))(Ph) H with 2-methoxythiophene, 3-methoxythiophene, 2-cyanothiophene, 3-cyanothiophene, 2-trimethylsilylthiophene, ethylenesulfide, trimethylenesulfide, and several polymethylthiophenes have been investigated. These thiophene derivatives give C-S and in one case C-H insertion products. Ethylene sulfide and trimethylene sulfide undergo ring opening or desulfurization. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.09.023
• 作为产物：
  描述：

  硫化环丙烷 、 [Rh(H)(Ph)(η5-pentamethylcyclopentadienyl)(PMe3)] 以 全氘代环己烷 为溶剂， 生成
  参考文献：
  名称：

  Bond cleavage reactions in substituted thiophenes by a rhodium complex

  摘要：

  The reactions of (C(5)Me(5)) Rh(PMe(3))(Ph) H with 2-methoxythiophene, 3-methoxythiophene, 2-cyanothiophene, 3-cyanothiophene, 2-trimethylsilylthiophene, ethylenesulfide, trimethylenesulfide, and several polymethylthiophenes have been investigated. These thiophene derivatives give C-S and in one case C-H insertion products. Ethylene sulfide and trimethylene sulfide undergo ring opening or desulfurization. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.09.023