(2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)Fe(μ-H)2BPh2 | 944160-03-6

• 英文名称: (2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)Fe(μ-H)2BPh2
• CAS: 944160-03-6
• 化学式: C₄₁H₅₃BFeN₂
• 分子量: 640.543
• InChiKey: PVSRKURGKRHAOA-VCGBEGQOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)Fe(μ-H)]2 、 三苯基硼烷 以 氘代苯 为溶剂， 生成 (2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)FePh 、 (2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)Fe(μ-H)2BPh2
  参考文献：
  名称：

  Borane B−C Bond Cleavage by a Low-Coordinate Iron Hydride Complex and N−N Bond Cleavage by the Hydridoborate Product

  摘要：

  The iron(II) hydride dimers [(LFe)-Fe-R(mu-H)(2)FeLR] (L-Me = 2,4-bis(2,6-diisopropylphenylimino)pent-3-yl; L-tBu = 2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimino)hept-4-yl) abstract hydrocarbyl groups from BR'(3) (R' = Et, Ph) to give (LFeR)-Fe-R' and (LFe)-Fe-R(mu-H)(2)BR'(2). Mechanistic studies with R = R' = Me are consistent with a process in which the hyride dimer opens one Fe-H bond, and subsequent B-H bond formation is concerted with dissociation of an Fe-H unit. Cleavage of boron-carbon bonds is likely to proceed at least in part from transient quaternary borate anions formed through disproportionation of HBEt3-. In a separate bond-breaking reaction, (LFe)-Fe-Me(mu-H)(2)BEt2 reacts with N2H4 to form a 1:1 adduct, which has been crystallographically characterized. Upon heating, it ejects H-2 from the bridging hydrides and cleaves the N-N bond to form the diaminoborate complex (LFe)-Fe-Me(mu-NH2)(2)BEt2. These novel bond-breaking reactions are facilitated by the low coordination number at the iron(II) center.

  DOI：

  10.1021/om7003805