dichloro (1,2,6,9,13,14-hexaaza-3,5,10,12-tetramethylcyclopentadecane-2,5,9,12-tetraene)nickel(II) | 797757-37-0

• 英文名称: dichloro (1,2,6,9,13,14-hexaaza-3,5,10,12-tetramethylcyclopentadecane-2,5,9,12-tetraene)nickel(II)
• CAS: 797757-37-0
• 化学式: C₁₃H₂₄Cl₂N₆Ni
• 分子量: 393.97
• InChiKey: UTRGJZJACSLSDO-KZMHRLLDSA-L

物化性质

• 熔点：
  281 °C

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 1,2,6,9,13,14-hexaaza-3,5,10,12-tetramethylcyclopentadecane-2,5,9,12-tetraene 以 甲醇 为溶剂， 以42%的产率得到dichloro (1,2,6,9,13,14-hexaaza-3,5,10,12-tetramethylcyclopentadecane-2,5,9,12-tetraene)nickel(II)
  参考文献：
  名称：

  Synthesis and Physico‐chemical Studies on a 15‐Membered Hexaaza Macrocyclic Ligand Derived from Hydrazine and Its Complexes with Co(II), Ni(II), Cu(II), and Zn(II)

  摘要：

  The macrocyclic ligand, 1,2,6,9,13,14-hexaaza-3,5,10,12-tetramethyl-cyclopentadecane-2,5,9,12-tetraene (L), has been prepared by the condensation reaction of hydrazine, formaldehyde, ethylenediamine, and 2,4-pentanedione in 2 : 1 : 1 : 2 molar ratio. Metal complexes of the type [MLX2] (M = Co(II), Ni(II), Cu(II), and Zn(II); X = Cl or NO3) have been synthesized by the reaction of L with the corresponding metal salts in methanol. The macrocyclic ligand (L) and its metal complexes have been characterized by elemental analyses, Fr-IR and H-1 and C-13 NMR spectral studies. The stereochemistry of the metal complexes have been deduced from magnetic moments and band positions in the electronic spectra.

  DOI：

  10.1081/sim-120039262