[Et2SnCl(4-(2-methoxyphenyl)piperazine-1-carboditioate)] | 1053183-56-4

• 英文名称: [Et2SnCl(4-(2-methoxyphenyl)piperazine-1-carboditioate)]
• 英文别名: Et2SnCl(MPPDA)
• CAS: 1053183-56-4
• 化学式: C₁₆H₂₅ClN₂OS₂Sn
• 分子量: 479.682
• InChiKey: RDTXBGDJOSAGKR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-(2-methoxyphenyl)piperazine-1-carboditioic acid 、 二乙基二氯化锡 以 甲醇 为溶剂， 以79%的产率得到[Et2SnCl(4-(2-methoxyphenyl)piperazine-1-carboditioate)]
  参考文献：
  名称：

  Synthesis, spectroscopic characterization, and crystal structures of two chlorodiorganotin(IV) 4-(2-methoxyphenyl)piperazine-1-carbodithioates

  摘要：

  Two chlorodiorganotin(IV) complexes of 4-(2-methoxyphenyl)piperazine-1-carbodithioate (MPPDA) have been synthesized by 1:1 mole-ratio reactions of the parent acid (MPPDAH) with Me2SnCl2 or Et2SnCl2 in dry methanol. The products have been characterized by Raman and multinuclear NMR (H-1, C-13 and Sn-119) spectroscopy, elemental analysis, and mass spectrometry. Single-crystal X-ray diffraction studies indicate that both complexes have distorted trigonal bipyramidal geometries around the central Sn atom. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.05.006