[(η5-C9Me7)Rh(CO)(C7H8COMe)][BF4] | 817628-63-0

• 英文名称: [(η5-C9Me7)Rh(CO)(C7H8COMe)][BF4]
• CAS: 817628-63-0
• 化学式: BF₄*C₂₆H₃₂O₂Rh
• 分子量: 566.249
• InChiKey: XKQDDHDOOGJLRZ-SAXMHUBASA-N

反应信息

• 作为产物：
  描述：

  [(η5-C9Me7)Rh(CO)2(Me)][BF4] 、 2,5-降冰片二烯 以 not given 为溶剂， 生成 [(η5-C9Me7)Rh(CO)(C7H8COMe)][BF4]
  参考文献：
  名称：

  Facile Alkene Insertion into a Rhodium(III)−Acetyl Bond:  Potential Catalysts for CO/Alkene Copolymerization

  摘要：

  Cationic Rh(III) methyl complexes, [(eta(5)-ligand)-Rh(CO)(2)Me](+) (eta(5)-ligand = C5Me5, C9Me7, C9Me3H4), undergo facile reactions with strained alkenes (e.g. norbornadiene) to give products resulting from insertion of the alkene into a Rh-acetyl bond. Kinetic, mechanistic, and structural results are presented, along with evidence of catalytic activity for CO/alkene copolymerization.

  DOI：

  10.1021/om049258e