[(Co2(CO)6(μ4,η2-HC2CH2O))2(CO)2] | 311772-71-1

• 英文名称: [(Co2(CO)6(μ4,η2-HC2CH2O))2(CO)2]
• CAS: 311772-71-1
• 化学式: C₂₀H₆Co₄O₁₆
• 分子量: 738.231
• InChiKey: YLJQQYSGIAKVFB-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  [dicarbonyldichlorodirhodium(I)] 、 [(Co2(CO)6(μ4,η2-HC2CH2O))2(CO)2] 以 苯 为溶剂， 以62.6%的产率得到[[Rh2Co2(CO)8(μ-CO)2(μ4,η2-HC2CH2O-)]2(C(O))2]
  参考文献：
  名称：

  Reactions of linked tetrahedron clusters [Co2(CO)6(μ-HC2CH2O)–]2R with Rh2(CO)4Cl2 to give mixed-metal linked alkyne-bridged butterfly clusters containing C2Co2Rh2 unit

  摘要：

  The reactions of compound Rh-2(CO)(4)Cl-2, 1 with [Co-2(CO)(6)(mu-HC2CH2O)-](2)R (R = C6H4, 2; (COCH2)(2), 3; C6H4-1,4-(CO)(2), 4; (COCH)(2), 5; (CO)(2), 6) in benzene at 60 degrees C produce five new mixed-metal linked clusters Rh2CO2(CO)(10)(mu(4),eta(2) -HC2CH2O-R-OCH2C2H-mu) OCH2C2H-mu) (R = C6H4, 7a; (COCH2)(2), 7b; C6H4-1,4-(CO)(2), 7c; (COCH)(2), 7d; (CO)2, 7e) and five known linked octahedral clusters [Rh2Co2)(CO)(10)(mu(4)eta(2)-HC2CH2O-)](2)R (R = C6H4, 8a; (COCH2)(2), 8b; C6H4-1,4-(CO)(2), 8c; (COCH)(2), 8d; (CO)(2), 8e), respectively. Treatment of clusters 7a-8e in benzene at room temperature under air for 24 h with stirring afford the precursor clusters 2-6, respectively. The structure of cluster 7a has been determined by single-crystal X-ray diffraction. The linked cluster 7a possesses two isomers A and B in its structures, the Rh-2(CO)(4) unit inserts into one of two Co-Co bonds and coordinates to the Co2C2 core forming one distorted closo-Rh2CO2C2 octahedron framework which is connected to the Co2C2 tetrahedron unit via C6H4(OCH2)(2)-1,4 as a bridging ligand. All clusters were characterized by C, H elemental analysis, IR and H-1 NMR spectroscopy. (c) 2005 Published by Elsevier B.V.

  DOI：

  10.1016/j.jorganchem.2005.09.014
• 作为产物：
  描述：

  [Rh2Co2(CO)10(μ4,η2-HC2CH2O(CO)2OCH2C2H-μ)Co2(CO)6] 在 air 作用下， 以 苯 为溶剂， 以29.8%的产率得到[(Co2(CO)6(μ4,η2-HC2CH2O))2(CO)2]
  参考文献：
  名称：

  Reactions of linked tetrahedron clusters [Co2(CO)6(μ-HC2CH2O)–]2R with Rh2(CO)4Cl2 to give mixed-metal linked alkyne-bridged butterfly clusters containing C2Co2Rh2 unit

  摘要：

  The reactions of compound Rh-2(CO)(4)Cl-2, 1 with [Co-2(CO)(6)(mu-HC2CH2O)-](2)R (R = C6H4, 2; (COCH2)(2), 3; C6H4-1,4-(CO)(2), 4; (COCH)(2), 5; (CO)(2), 6) in benzene at 60 degrees C produce five new mixed-metal linked clusters Rh2CO2(CO)(10)(mu(4),eta(2) -HC2CH2O-R-OCH2C2H-mu) OCH2C2H-mu) (R = C6H4, 7a; (COCH2)(2), 7b; C6H4-1,4-(CO)(2), 7c; (COCH)(2), 7d; (CO)2, 7e) and five known linked octahedral clusters [Rh2Co2)(CO)(10)(mu(4)eta(2)-HC2CH2O-)](2)R (R = C6H4, 8a; (COCH2)(2), 8b; C6H4-1,4-(CO)(2), 8c; (COCH)(2), 8d; (CO)(2), 8e), respectively. Treatment of clusters 7a-8e in benzene at room temperature under air for 24 h with stirring afford the precursor clusters 2-6, respectively. The structure of cluster 7a has been determined by single-crystal X-ray diffraction. The linked cluster 7a possesses two isomers A and B in its structures, the Rh-2(CO)(4) unit inserts into one of two Co-Co bonds and coordinates to the Co2C2 core forming one distorted closo-Rh2CO2C2 octahedron framework which is connected to the Co2C2 tetrahedron unit via C6H4(OCH2)(2)-1,4 as a bridging ligand. All clusters were characterized by C, H elemental analysis, IR and H-1 NMR spectroscopy. (c) 2005 Published by Elsevier B.V.

  DOI：

  10.1016/j.jorganchem.2005.09.014