tetrabenzyl 1,1'-ferocene-bis-(N-diphenylmethylaminomethanephosphonate) | 695230-50-3

• 英文名称: tetrabenzyl 1,1'-ferocene-bis-(N-diphenylmethylaminomethanephosphonate)
• CAS: 695230-50-3
• 化学式: C₆₆H₆₂FeN₂O₆P₂
• 分子量: 1097.02
• InChiKey: SUVMEUIKCPBHRY-ODFNULCSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,1'-ferocene-bis-(carbaldehyde-N-diphenylmethylimine) 、 亚磷酸二苄酯 以 甲苯 为溶剂， 以47%的产率得到tetrabenzyl 1,1'-ferocene-bis-(N-diphenylmethylaminomethanephosphonate)
  参考文献：
  名称：

  First synthesis of 1,1′-ferrocene bis-aminophosphonic esters

  摘要：

  The series of aminophosphonates bearing the 1,1'-bis-substituted ferrocenyl moiety was obtained by the addition of dialkyl phosphites to an azomethine bond of Schiff bases derived from 1,1'-ferrocene-bis-carboxaldehyde. This addition led to both diastereoisomeric forms demonstrating its behaviour to be contrary to the addition to terephthalic Schiff bases, which led exclusively to a meso-form. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.01.012