[Cu(2,2'-bis[[(3,5-dimethylpyrazol-1-yl)methyl]amino]-1,1'-biphenyl)(Cl)]Cl | 1132653-72-5

• 英文名称: [Cu(2,2'-bis[[(3,5-dimethylpyrazol-1-yl)methyl]amino]-1,1'-biphenyl)(Cl)]Cl
• CAS: 1132653-72-5
• 化学式: C₂₄H₂₈ClCuN₆*Cl
• 分子量: 534.979
• InChiKey: XPIGTOREZRRJSX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 2,2'-bis[[(3,5-dimethylpyrazol-1-yl)methyl]amino]-1,1'-biphenyl 以 甲醇 为溶剂， 以36.5%的产率得到[Cu(2,2'-bis[[(3,5-dimethylpyrazol-1-yl)methyl]amino]-1,1'-biphenyl)(Cl)]Cl
  参考文献：
  名称：

  Copper(II) complexes of a biphenyl-based ligand: Tuning the needs of the metal with those of the ligand

  摘要：

  The novel pyrazole-containing tetradentate ligand 2,2'-bis[[(3,5-dimethylpyrazol-1-yl)methyl]amino]-1,1'-biphenyl (N-4-mpz), 1, was synthesized and three Cu(II) complexes, 2-4, were prepared from this compound. These complexes were characterized by a combination of elemental analysis, FAB-MS and electrochemistry and were shown to have the structure of [Cu(N-4-mpz)(Pz)]X-2 where X = BF4 or ClO4 or [Cu(N-4-mpz)(Cl)]Cl. The X-ray Structure of [Cu(N-4-mpz)(Pz)] (ClO4)(2)center dot CH3OH, 2, was determined and it showed the Cu(II) coordinated by the four nitrogen donors from the ligand along with an exogenous pyrazole donor that had been extracted from another molecule of the ligand. Cyclic voltammetry studies indicated that the complexes undergo quasi-reversible one-electron reductions in acetonitrile at potentials between 396 and 422 mV versus Ag/AgCl. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.11.034