In((2-dimethylaminomethyl)pyrrolate)2Cl | 878027-79-3

• 英文名称: In((2-dimethylaminomethyl)pyrrolate)2Cl
• CAS: 878027-79-3
• 化学式: C₁₄H₂₂ClInN₄
• 分子量: 396.628
• InChiKey: DQTFTNSVKCUSTE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  In((2-dimethylaminomethyl)pyrrolate)2Cl 、 lithium phenylacetylide 以 乙醚 为溶剂， 以81%的产率得到In[(2-dimethylaminomethyl)pyrrolate]2C2Ph
  参考文献：
  名称：

  Indium complexes incorporating bidentate substituted pyrrole ligand: Synthesis, characterization, and ring-opening polymerization of ε-caprolactone

  摘要：

  The reactions of InCl3 with two and three equivalents of lithium (2-dimethylaminomethyl)pyrrolate (1) in diethyl ether solutions afford In[C4H3N(CH2NMe2)](2)CI (2) and III [C4H3N(CH2NMe2)](3) (3) in 92% and 50% yield, respectively. Subsequent reactions of 2 with MeLi and Li(C equivalent to CPh) yield In[C4H3N(CH2NMe2)](2)Me (4) and In[C4H3N(CH2NMe2)](2)(C equivalent to CPh) (5), respectively. All compounds were confirmed by H-1 and C-13 NMR spectroscopy and compounds 3, 4, and 5 were further characterized by single-crystal X-ray crystallography. Compounds 2, 3, and 4 showed moderate catalytic activity toward the ring-opening polymerization of E-caprolactone. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.09.054
• 作为产物：
  描述：

  氯化铟 、 lithium (2-dimethylaminomethyl)pyrrolate 以 乙醚 为溶剂， 以92%的产率得到In((2-dimethylaminomethyl)pyrrolate)2Cl
  参考文献：
  名称：

  Indium complexes incorporating bidentate substituted pyrrole ligand: Synthesis, characterization, and ring-opening polymerization of ε-caprolactone

  摘要：

  The reactions of InCl3 with two and three equivalents of lithium (2-dimethylaminomethyl)pyrrolate (1) in diethyl ether solutions afford In[C4H3N(CH2NMe2)](2)CI (2) and III [C4H3N(CH2NMe2)](3) (3) in 92% and 50% yield, respectively. Subsequent reactions of 2 with MeLi and Li(C equivalent to CPh) yield In[C4H3N(CH2NMe2)](2)Me (4) and In[C4H3N(CH2NMe2)](2)(C equivalent to CPh) (5), respectively. All compounds were confirmed by H-1 and C-13 NMR spectroscopy and compounds 3, 4, and 5 were further characterized by single-crystal X-ray crystallography. Compounds 2, 3, and 4 showed moderate catalytic activity toward the ring-opening polymerization of E-caprolactone. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.09.054