| 848899-38-7

• CAS: 848899-38-7
• 化学式: C₂₇H₂₁Cl₃Cu₂N₆O
• 分子量: 678.954
• InChiKey: AKVPTYATQVNTRM-URJGFBTJSA-J

反应信息

• 作为产物：
  描述：

  、 copper dichloride 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  New binuclear metal chelate complexes of copper(II) chloride and acetate with bis(hetarylhydrazones) obtained by condensation of 2,6-diformyl-4-r-phenols with 2-hydrazinoquinoline

  摘要：

  分光光度法研究了异配体铬（III）与亚氨基二乙酸（H2Ida）、N-甲基亚氨基二乙酸（H2Mida）、N-（β-羟乙基）亚氨基二乙酸（H2Heida）、次氮基三乙酸（H3Nta）、乙二胺四乙酸（H4Edta）和柠檬酸（H4Cit）的络合物、乙二胺四乙酸（H4Edta）和柠檬酸（H4Cit）表明，三元体系中的络合取决于试剂的浓度和介质的 pH 值。它们的稳定常数对数分别为 41.97 ±0.47、43.54 ±0.62、42.32 ±0.62、36.34 ±0.26、43.70 ±0.25、39.75 ±0.45、32.93 ±1.56、46.46 ±0.80、41.71 ±0.81（I = 0.1（NaClO 4））。

  DOI：

  10.1007/s11173-005-0012-7

文献信息

• New Binuclear Cu(II) Complexes with Bis(hetarylhydrazones) of 2,6-Diformyl-4-Methylphenol
  作者：V. V. Lukov、E. V. Dontsova、S. V. Posokhova、L. D. Popov、V. A. Kogan

  DOI：10.1023/b:ruco.0000047472.21474.e0

  日期：2004.11

  A series of new binuclear complexes of copper(II) acetate and chloride with bis(hydrazones) based on heterocyclic hydrazines were synthesized. Magnetochemical analysis showed that the resulting metal chelates with different bridging atoms in the exchanged fragment significantly differ in exchange parameters. This fact was explained in terms of geometrical structures of complexes of both types.