2,4,6,7-tetra-t-butyl-1,5-dimethyl-3,3-dichloro-2,4,6-triaza-7-azonia-1,5-disila-3λ(4)-indabicyclo{3.1.1}heptane | 134042-16-3

• 英文名称: 2,4,6,7-tetra-t-butyl-1,5-dimethyl-3,3-dichloro-2,4,6-triaza-7-azonia-1,5-disila-3λ(4)-indabicyclo{3.1.1}heptane
• CAS: 134042-16-3
• 化学式: C₁₈H₄₃Cl₂InN₄Si₂
• 分子量: 557.463
• InChiKey: GNESYKBCZGSWBG-YUDITJGDSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氯化铟 、 cis-1,3-Di-tert-butyl-2,4-bis(tert-butylamino)-2,4-dimethyl-1,3,2,4-diazadisiletidin 在 n-butyl lithium 作用下， 以 正己烷 为溶剂， 以60%的产率得到2,4,6,7-tetra-t-butyl-1,5-dimethyl-3,3-dichloro-2,4,6-triaza-7-azonia-1,5-disila-3λ(4)-indabicyclo{3.1.1}heptane
  参考文献：
  名称：

  Spezielle Silazanderivate von Digallan(4) and Diindan(4) mit GaGa- bzw. InIn-Bindung

  摘要：

  Al, Ga and In can easily be incorporated in the cyclic silazane (MeSi)2 (N(t)Bu)4H-2 (LH2) through formal substitution of the hydrogen atoms by the metallic elements. LAlMe, LAlCl, LGaCl, LInCl as well as the side product L(H)InCl2 are obtained in high yields. X-ray structure determinations confirm the molecules LAlMe and L(H)InCl2 to be polycyclic and the metallic atoms to be four-coordinated by intramolecular nitrogen donors. When LAlCl, LGaCl and LInCl are reduced by sodium naphthalene, in the two latter cases the formation of LGa-GaL and LIn-InL is observed. An X-ray structure determination of LIn-InL shows an In-In bond of 2.768(1) angstrom with the two indium atoms being coordinated by three nitrogen atoms each (In-N ranging from 2.12(1)-2.298(7) angstrom). LGa-GaL and LIn-InL can be considered as the first amides of Ga(II) and In(II).

  DOI：

  10.1016/0022-328x(91)83176-5