3,3'-bis(N-ferrocenylmethyleneformylhydrazone)-2,2'-bipyridyl | 850621-24-8

• 英文名称: 3,3'-bis(N-ferrocenylmethyleneformylhydrazone)-2,2'-bipyridyl
• CAS: 850621-24-8
• 化学式: C₃₄H₂₈Fe₂N₆O₂
• 分子量: 664.329
• InChiKey: GJSXLSPTXCMCPZ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  hydrated mercury(II) acetate 、 3,3'-bis(N-ferrocenylmethyleneformylhydrazone)-2,2'-bipyridyl 以 乙醇 、 乙腈 为溶剂， 以60%的产率得到[Hg2(3,3'-bis(N-ferrocenylmethyleneformylhydrazone)-2,2'-bipyridyl(2-))(H2O)2(acetato)2]
  参考文献：
  名称：

  Synthesis and Characterization of 3,3′‐bis(N‐Ferrocenyl methylene formylhydrazone)‐2,2′‐bipyridyl and its Cd(II), Hg(II), Cu(II), and Mn(II) Complexes

  摘要：

  In this article, 3,3'-bis(N-ferrocenylmethylene formylhydrazone)-2,2'-bipyridyl and its Cd(II), Hg(II), Cu(II), and Mn(II) complexes have been synthesized and characterized by elemental analyses, IR, H-1 NMR spectral, thermal analyses, and molar conductances. In the complexes, 3,3'-bis(N-ferrocenylmethylene formylhydrazone)-2,2'-bipyridyl coordinates to the transition metal ions using a methylenimine nitrogen, the amide oxygen in the enolic form, the pyridyl nitrogen, the acetate in a symmetrical bidentate manner, and one water molecule, all of which participate in coordination to form a binuclear complex. The ligand and the complexes are insoluble in common organic solvents and slightly soluble in strongly polar solvents such as DMF and DMSO.

  DOI：

  10.1081/sim-200030165
• 作为产物：
  描述：

  6,6'-dicarboxylic acid hydrazide-2,2'-bipyridine 、 二茂铁甲醛 以 乙醇 为溶剂， 以65%的产率得到3,3'-bis(N-ferrocenylmethyleneformylhydrazone)-2,2'-bipyridyl
  参考文献：
  名称：

  Synthesis and Characterization of 3,3′‐bis(N‐Ferrocenyl methylene formylhydrazone)‐2,2′‐bipyridyl and its Cd(II), Hg(II), Cu(II), and Mn(II) Complexes

  摘要：

  In this article, 3,3'-bis(N-ferrocenylmethylene formylhydrazone)-2,2'-bipyridyl and its Cd(II), Hg(II), Cu(II), and Mn(II) complexes have been synthesized and characterized by elemental analyses, IR, H-1 NMR spectral, thermal analyses, and molar conductances. In the complexes, 3,3'-bis(N-ferrocenylmethylene formylhydrazone)-2,2'-bipyridyl coordinates to the transition metal ions using a methylenimine nitrogen, the amide oxygen in the enolic form, the pyridyl nitrogen, the acetate in a symmetrical bidentate manner, and one water molecule, all of which participate in coordination to form a binuclear complex. The ligand and the complexes are insoluble in common organic solvents and slightly soluble in strongly polar solvents such as DMF and DMSO.

  DOI：

  10.1081/sim-200030165