[Ru2(CO)6(μ-η2,η4-(Me3Si)C=C(SC(ferrocenyl)=C(SCCSiMe3)C(H)=C(ferrocenyl))C=C(ferrocenyl))] | 1107664-84-5

• 英文名称: [Ru2(CO)6(μ-η2,η4-(Me3Si)C=C(SC(ferrocenyl)=C(SCCSiMe3)C(H)=C(ferrocenyl))C=C(ferrocenyl))]
• CAS: 1107664-84-5
• 化学式: C₅₂H₄₆Fe₃O₆Ru₂S₂Si₂
• 分子量: 1256.92
• InChiKey: CDGGVJDOUAODSN-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  二茂铁乙炔 、 [Ru2(CO)6(μ3-η2,η4,η3-(Me3Si)C=C(SC(ferrocenyl)=C(SCCSiMe3)Ru(CO)3)C=C(ferrocenyl))] 以 甲苯 为溶剂， 以14%的产率得到[Ru2(CO)6(μ-η2,η4-(Me3Si)C=C(SC(ferrocenyl)=C(SCCSiMe3)C(H)=C(ferrocenyl))C=C(ferrocenyl))]
  参考文献：
  名称：

  Ferrole-type compounds containing thiophenic or thiepinic rings in the 3,4-positions of the metallacycle

  摘要：

  The new ferrole Fe(2)(CO)(6)[mu-eta(2), eta(4)-(Fc)C=C{C(H)=C(R)S}C=C(SiMe(3))] [R = SiMe(3) (1) and R = Fc (2)] and ruthenoles Ru(2)(CO)(6)[mu-eta(2), eta(4)-(Me(3)Si)C=C{SC(Fc)=C(H)}C=C(Fc)](3) and Ru(2)(CO)(6)[mu-eta(2), eta(4)-(Me(3)Si)C=C (SC CFc)C(H)=C(Fc)]4, have been obtained from the reactions of M(3)(CO)(12) (M = Fe, Ru) and FcC CSC CSiMe(3) through S-C bond activations and C-C coupling reactions. Thermolysis of Ru(2)(CO)(6)[mu(3)-eta(2), eta(4), eta(3)-(Me(3)Si)C=C{SC(Fc)=C(SC CSiMe(3)}Ru(CO)(3)}C=C(Fc)] alone and in the presence of HC CFc, yielded the compounds Ru(2)(CO)(6)[mu-eta(2), eta(4)-(Me(3)Si)C=C{SC(Fc)=C(SC CSiMe(3))}C=C(Fc)] 5 and Ru(2)(CO)(6)[mu-eta(2),eta(4)-(Me(3)Si)C=C{SC(Fc)=C(SC CSiMe(3))C(H)=C(Fc)}C=C(Fc)] 6, respectively. The crystal structures of the compounds 1, 3, 4 and 6 are reported. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.10.011