[Pd(C2H5OC6H3CHNC6H4OC2H5)]3(μ3-O2CC2H5)(μ3-S) | 671192-26-0

• 英文名称: [Pd(C2H5OC6H3CHNC6H4OC2H5)]3(μ3-O2CC2H5)(μ3-S)
• CAS: 671192-26-0
• 化学式: C₅₄H₅₉N₃O₈Pd₃S
• 分子量: 1229.4
• InChiKey: AOSWTOJCBQOJHK-IFBVWEAISA-M

反应信息

• 作为产物：
  描述：

  [Pd2(μ-OH)2(p-C2H5OC6H3CH=NC6H4OC2H5-p)2] 以 not given 为溶剂， 生成 [Pd(C2H5OC6H3CHNC6H4OC2H5)]3(μ3-O2CC2H5)(μ3-S)
  参考文献：
  名称：

  Formation of Trinuclear Palladium Orthometalated Complexes with Unprecedented Asymmetrical (μ₃-S)(μ₃-X) Bridges (X = OH, SR, O₂CR) from μ₂-Hydroxo Dimeric Complexes and CS₂

  摘要：

  Complexes [Pd-3(mu(3)-S)(mu(3)-X)(L)(3)] (L = orthometalated imine), obtained by an unusual reaction of mu(2)-OH dimeric complexes and CS2, are an unprecedented type of asymmetrical bridges between metallatriangles, which force an all-cis arrangement of the three orthometalated ligands relative to the metallatriangle.

  DOI：

  10.1021/ic0351085