Cu2(2-[(3-methylaminopropylimino)methyl]-phenol(-1H))2(μ-1,1-N3)2 | 1234506-69-4

• 英文名称: Cu2(2-[(3-methylaminopropylimino)methyl]-phenol(-1H))2(μ-1,1-N3)2
• CAS: 1234506-69-4
• 化学式: C₂₂H₃₀Cu₂N₁₀O₂
• 分子量: 593.638
• InChiKey: XHARQYYFYMKUJC-WNVHQAKYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Cu2(2-[(3-methylaminopropylimino)methyl]-phenol(-1H))2(μ-1,1-N3)2 、 sodium azide 以 甲醇 为溶剂， 生成 Cu2(2-[(3-methylaminopropylimino)methyl]-phenol(-1H))2(μ-1,1-N3)2*H2O
  参考文献：
  名称：

  A rare case of solution and solid state inter-conversion of two copper(II) dimers and a copper(II) chain

  摘要：

  Three Cu(II)-azido complexes of formula [Cu2L2(N-3)(2)] (1), [Cu2L2(N-3)(2)]center dot H2O (2) and [CuL(N-3)](n) (3) have been synthesized using the same tridentate Schiff base ligand HL (2-[(3-methylaminopropylimino)-methyl]-phenol), the condensation product of N-methyl-1,3-propanediamine and salicyldehyde). Compounds 1 and 2 are basal-apical mu-1,1 double azido bridged dimers. The dimeric structure of 1 is centro-symmetric but that of 2 is non-centrommetric. Compound 3 is a mu-1,1 single azido bridged 1D chain. The three complexes interconvert in solution and can be obtained in pure form by carefully controlling the synthetic conditions. Compound 2 undergoes an irreversible transformation to 1 upon dehydration in the solid state. The magnetic properties of compounds 1 and 2 show the presence of weak antiferromagnetic exchange interactions mediated by the double 1,1-N-3 azido bridges (J = -2.59(4) and -0.10(1) cm-(1), respectively). The single 1,1-N-3 bridge in compound 3 mediates a negligible exchange interaction. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.07.027
• 作为产物：
  描述：

  Cu2(2-[(3-methylaminopropylimino)methyl]-phenol(-1H))2(μ-1,1-N3)2*H2O 以 甲醇 为溶剂， 生成 Cu2(2-[(3-methylaminopropylimino)methyl]-phenol(-1H))2(μ-1,1-N3)2
  参考文献：
  名称：

  A rare case of solution and solid state inter-conversion of two copper(II) dimers and a copper(II) chain

  摘要：

  Three Cu(II)-azido complexes of formula [Cu2L2(N-3)(2)] (1), [Cu2L2(N-3)(2)]center dot H2O (2) and [CuL(N-3)](n) (3) have been synthesized using the same tridentate Schiff base ligand HL (2-[(3-methylaminopropylimino)-methyl]-phenol), the condensation product of N-methyl-1,3-propanediamine and salicyldehyde). Compounds 1 and 2 are basal-apical mu-1,1 double azido bridged dimers. The dimeric structure of 1 is centro-symmetric but that of 2 is non-centrommetric. Compound 3 is a mu-1,1 single azido bridged 1D chain. The three complexes interconvert in solution and can be obtained in pure form by carefully controlling the synthetic conditions. Compound 2 undergoes an irreversible transformation to 1 upon dehydration in the solid state. The magnetic properties of compounds 1 and 2 show the presence of weak antiferromagnetic exchange interactions mediated by the double 1,1-N-3 azido bridges (J = -2.59(4) and -0.10(1) cm-(1), respectively). The single 1,1-N-3 bridge in compound 3 mediates a negligible exchange interaction. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.07.027