(N-isopropyl-N-2-ethylpyridine)AuCl2(AuCl4) | 917499-97-9

• 英文名称: (N-isopropyl-N-2-ethylpyridine)AuCl2(AuCl4)
• CAS: 917499-97-9
• 化学式: AuCl₄*C₁₀H₁₆AuCl₂N₂
• 分子量: 770.901
• InChiKey: RPJDMXTYSBXYJB-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  sodium tetrachloroaurate(III) dihyrate 、 2-Isopropylamino-1-(α-pyridyl)-ethan 以 水 为溶剂， 以24%的产率得到(N-isopropyl-N-2-ethylpyridine)AuCl2(AuCl4)
  参考文献：
  名称：

  A robust dimethylgold(III) complex stabilized by a 2-pyridyl-2-pyrrolide ligand

  摘要：

  Reaction of isopropyl[(2-pyridyl)alkyl]amines such as N-isopropyl-N-2-methylpyridine or N-isopropyl-N-2-ethylpyridine with aqueous solutions of NaAuCl4 led to the formation of [LAUCl(2)][AuCl4] in low yields, where L = pyridyl amine bound to gold in a bidentate fashion. Reaction of 2-(3,5-diphenyl-1H-pyrrol-2-yl)pyridine with aqueous NaAuCl4, however, proceeded with formal loss of HCl and direct formation of the gold(III) amido complex L'AuCl2, where L' = deprotonated pyrrolyl ligand. Optimization of the reaction conditions to make the new amido complex identified MeCN:H2O (1:2) as the best choice of solvent, affording product in 92% yield. This dichloro amido complex is a convenient precursor to 'AuMe2, which was found to be air-stable and thermally robust. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.08.083