[Me2Ga(N(isopropyl)SnMe3)]2 | 174837-76-4

• 英文名称: [Me2Ga(N(isopropyl)SnMe3)]2
• CAS: 174837-76-4
• 化学式: C₁₆H₄₄Ga₂N₂Sn₂
• 分子量: 641.405
• InChiKey: VTSANWWMLUCQAR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  Bis(trimethylstannyl)-isopropylamin 、 三甲基镓 以 neat (no solvent) 为溶剂， 以69.1%的产率得到[Me2Ga(N(isopropyl)SnMe3)]2
  参考文献：
  名称：

  Synthesis of Substituted Aminogallanes by Alkyltrimethyltin Elimination

  摘要：

  Alkyltrimethyltin elimination reactions of R(3)Ga (R = Me, Et) with R '' R'NSnMe(3) (R '' = i-Bu, SnMe(3), C6H11 and R' = i-Bu, i-Pr, C6H11) have been investigated. The aminogallanes [Me(2)GaN(i-Bu)(2)](2), [Et(2)GaN(i-Bu)(2)](2), [Me(2)GaN(i-Pr)SnMe(3)](2), [Me(2)GaN(C6H11)(2)](2), and [Et(2)GaN(C6H11)(2)](2) were isolated in 88.6, 68.6, 69.1, 81.0, and 80.4% yields, respectively. X-ray crystallographic studies of [Et(2)GaN(i-Bu)(2)](2), [Me(2)GaN(i-Pr)SnMe(3)](2), [Me(2)GaN(C6H11)(2)](2), and [Et(2)GaN(C6H11)(2)](2) indicate that the four aminogallanes are dimeric in the solid state. The four-membered (Ga-N)(2) rings in [Et(2)GaN(i-Bu)(2)](2) and [Et(2)GaN(C6H11)(2)](2) (molecules 1 and 2) are nonplanar with fold angles on the Ga ... Ga diagonals of 148.7(3) and 146.3(3), 147.7 (3)degrees. All five aminogallanes exist as dimers in benzene solutions. The H-1 and C-13 NMR spectra are reported and discussed.

  DOI：

  10.1021/om950812h