but-1-en-3-yn-2-yl(triphenyl)phosphanium;cyclopenta-1,3-diene;ruthenium(2+);triphenylphosphane;hexafluorophosphate | 177985-83-0

• 英文名称: but-1-en-3-yn-2-yl(triphenyl)phosphanium;cyclopenta-1,3-diene;ruthenium(2+);triphenylphosphane;hexafluorophosphate
• CAS: 177985-83-0
• 化学式: C₆₃H₅₂P₃Ru*F₆P
• 分子量: 1148.06
• InChiKey: DCMAUWSTZILMPE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  but-1-en-3-yn-2-yl(triphenyl)phosphanium;cyclopenta-1,3-diene;ruthenium(2+);triphenylphosphane;hexafluorophosphate 在 HPF₆ 作用下， 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Alkenylvinylidene and allenylidene complexes: evidence for the formation of a metal–trienylidene intermediate

  摘要：

  Reactions of [Ru(thf)(PPh(3))(2)(eta-C5H5)][PF6] with buta-1,4-diyne in the presence of nucleophiles give alkenylvinylidene or allenylidene complexes; the results are rationalised in terms of the formation of the intermediate trienylidene cation [Ru(C=C=C=CH2)(PPh(3))(2)(eta-C5H5)](+) which undergoes nucleophilic addition at C-gamma; the X-ray structure of the heteroallenylidene [Ru{C=C=CMe(NPh(2))}(PPh(3))(2)(eta-C5H5)][PF6] 2 is determined.

  DOI：

  10.1039/cc9960001009
• 作为产物：
  描述：

  丁二炔 、 [Ru(tetrahydrofuran)(triphenylphosphine)2(η5-C5H5)]PF6 、 三苯基膦 以 not given 为溶剂， 生成 but-1-en-3-yn-2-yl(triphenyl)phosphanium;cyclopenta-1,3-diene;ruthenium(2+);triphenylphosphane;hexafluorophosphate
  参考文献：
  名称：

  Alkenylvinylidene and allenylidene complexes: evidence for the formation of a metal–trienylidene intermediate

  摘要：

  Reactions of [Ru(thf)(PPh(3))(2)(eta-C5H5)][PF6] with buta-1,4-diyne in the presence of nucleophiles give alkenylvinylidene or allenylidene complexes; the results are rationalised in terms of the formation of the intermediate trienylidene cation [Ru(C=C=C=CH2)(PPh(3))(2)(eta-C5H5)](+) which undergoes nucleophilic addition at C-gamma; the X-ray structure of the heteroallenylidene [Ru{C=C=CMe(NPh(2))}(PPh(3))(2)(eta-C5H5)][PF6] 2 is determined.

  DOI：

  10.1039/cc9960001009