cis,meso-{Pt2Cl4(1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetraphosphadecane)} | 146165-40-4

• 英文名称: cis,meso-{Pt2Cl4(1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetraphosphadecane)}
• CAS: 146165-40-4
• 化学式: C₄₂H₄₂Cl₄P₄Pt₂
• 分子量: 1202.66
• InChiKey: HYJHLWMEUWTOLI-INQPFNRSSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  {Pt2Cl3(1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetraphosphadecane)}Cl 以 甲醇 、 二氯甲烷 为溶剂， 以87.5%的产率得到cis,meso-{Pt2Cl4(1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetraphosphadecane)}
  参考文献：
  名称：

  Binuclear platinum(II) complexes containing 1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetraphosphadecane (P4): first X-ray structure of a tetraphos dimer

  摘要：

  Several binuclear Pt(II) complexes containing 1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetraphosphadecane (tetraphos-1, P4) have been prepared and characterized by (P{H})-P-31-H-1 NMR spectroscopy, elemental analyses, melting points and an X-ray structure analysis. In the first steps of the syntheses complexes of the general formula rac- or meso-[Pt2Cl3P4]X (X=Cl-, (BF4-), (BPh4-)) (1-6) showing a cis P4 arrangement are formed. Transformation to thermodynamically more stable compounds (1a-6a) leads to the incorporation of the chloride anion in cis, rac- or cis, meso-[Pt2Cl4P4] (1a, 2a). The X-ray structure of 1a, which is the first structure of a tetraphos dimer, has been determined (tetragonal, P42(1)cBAR; a=17.257(2), c=16.048(3) angstrom, R=0.048 for 1107 observed reflections (F>6.0-sigma(F)). It shows an open-mode dimer with a Pt-Pt distance of 6.338(1) angstrom and a cis P4 configuration. In the presence of non-coordinating anions a rearrangement of P4 from cis to trans occurs (3a-6a). The observation that P4 is able to coordinate two metal centers in a cis as well as in a trans manner is unusual for binuclear oligophosphine complexes.

  DOI：

  10.1016/s0020-1693(00)85522-x