[Ru(1,4-cyanobenzene)(triphenylphosphine)2(Cp)][PF6] | 870543-77-4

• 英文名称: [Ru(1,4-cyanobenzene)(triphenylphosphine)2(Cp)][PF6]
• CAS: 870543-77-4
• 化学式: C₄₉H₃₉N₂P₂Ru*F₆P
• 分子量: 963.844
• InChiKey: XSVPUPSOIVCWRI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  二(三苯基膦)环戊二烯基氯化钌(II) 、 二氯甲烷 、 [Ru(1,4-cyanobenzene)(triphenylphosphine)2(Cp)][PF6] 以 not given 为溶剂， 生成 [[Ru(triphenylphosphine)2(Cp)]2(μ-1,4-NCC6H4CN][PF6]2*2CH2Cl2
  参考文献：
  名称：

  Syntheses and molecular structures of group 8 benzonitrile complexes

  摘要：

  The molecular structures of eight nitrite complexes of general form [M(NCC6H4R-4)(L-2)Cp']PF6 [M = Fe, Ru; L-2 = dppe, (PPh3)(2); Cp' = Cp Cp*] are reported and discussed in terms of the nature of the M-N interaction. Data are consistent with a predominantly a-interaction, similar to that found in related acetylide complexes, with little evidence for metal to nitrite pi-back bonding interactions. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.08.002
• 作为产物：
  描述：

  对苯二腈 、 ammonium hexafluorophosphate 、 二(三苯基膦)环戊二烯基氯化钌(II) 以 甲醇 为溶剂， 以75%的产率得到[Ru(1,4-cyanobenzene)(triphenylphosphine)2(Cp)][PF6]
  参考文献：
  名称：

  Syntheses and molecular structures of group 8 benzonitrile complexes

  摘要：

  The molecular structures of eight nitrite complexes of general form [M(NCC6H4R-4)(L-2)Cp']PF6 [M = Fe, Ru; L-2 = dppe, (PPh3)(2); Cp' = Cp Cp*] are reported and discussed in terms of the nature of the M-N interaction. Data are consistent with a predominantly a-interaction, similar to that found in related acetylide complexes, with little evidence for metal to nitrite pi-back bonding interactions. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.08.002