[2,6-i-Pr2-C6H3NC(CH3)C(CH3)NC6H3-2,6-i-Pr2]MoCl2 | 884842-80-2

• 英文名称: [2,6-i-Pr2-C6H3NC(CH3)C(CH3)NC6H3-2,6-i-Pr2]MoCl2
• CAS: 884842-80-2
• 化学式: C₂₈H₄₀Cl₂MoN₂
• 分子量: 571.485
• InChiKey: JBYZQKONVBNCIL-GGVBBUNRSA-L

反应信息

• 作为产物：
  描述：

  1,4-di(2,6-diisopropylphenyl)-2,3-dimethyl-1,4-diazabutadiene 、 tetrachlorobis(tetrahydrofurano)molybdenum(IV) 在 Zn 作用下， 以 二氯甲烷 为溶剂， 以67%的产率得到[2,6-i-Pr2-C6H3NC(CH3)C(CH3)NC6H3-2,6-i-Pr2]MoCl2
  参考文献：
  名称：

  Synthesis and crystal structure of tetracoordinated molybdenum (II) complexes containing rigid α-diimine ligands

  摘要：

  The complex of the general formula (dad)MoCl2 [3ai, 3bi, 3c] (dad = R'N=C(R)-C(R)=NR') is obtained in one step by reduction of [MoCl4(thf)(2)] (1) in the presence of dad ligands (dab: ai, Ar-BIAN: bi, Ph-BIC: c) (2). All new complexes have been characterized by IR and NMR spectroscopy. The X-ray single-crystal diffraction of 3a2 reveals a relatively tetrahedral coordination geometry. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.08.027