| 158364-54-6

• CAS: 158364-54-6
• 化学式: H₂NS
• 分子量: 48.0886
• InChiKey: DKZQKRVSFGLOMM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.59
• 重原子数：
  2.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26.02
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  Sulfanylium 、 氨 生成
  参考文献：
  名称：

  Huntress, W. T., Astrophysical Journal, Supplement Series, 1977, vol. 33, p. 495 - 514

  摘要：

  DOI：

文献信息

• Reactions of the H_<i>n</i>S⁺ ions (<i>n</i> = 0 to 3) with several molecular gases at thermal energies
  作者：David Smith、Nigel G. Adams、Werner Lindinger

  DOI：10.1063/1.442498

  日期：1981.10

  The rate coefficients and product ion distributions have been determined at room temperature for the reactions of the ions HnS+ (n = 0 to 3) with several diatomic and polyatomic gases. The reactions generally proceed at or near the collisional limit, often generating multiple products. Charge transfer, proton transfer, and atom abstraction, in some cases occurring in parallel, are evident within the data array, emphasizing the complexity of these reactions. The results obtained for the near-thermoneutral reactions of S+ and HS+ with H2S have provided values for the recombination energies of HS+ and H2S+ ions which, within the limitations of the assumptions made, are more closely defined than the previous values.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: S: SVol.4a/b, 5.1.3, page 469 - 471
  作者：

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: S: SVol.4a/b, 1.3.8.3, page 195 - 200
  作者：

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: S: SVol.4a/b, 1.3.8.5, page 204 - 205
  作者：

  DOI：——

  日期：——
• An experimental survey of the reactions of NH_<i>n</i>⁺ ions (<i>n</i> = 0 to 4) with several diatomic and polyatomic molecules at 300 K
  作者：Nigel G. Adams、David Smith、John F. Paulson

  DOI：10.1063/1.438893

  日期：1980.1

  A study has been made of the binary reactions at 300 K in a SIFT apparatus of the ions N+, NH+, NH2+, NH3+, and NH4+ with CH3NH2, NO, NH3, H2S, CH3OH, H2CO, COS, O2, H2O, CH4, CO2, CO,H2, and N2. The N+, NH+, and NH2+ reactions are generally fast, their rate coefficients being close to the collisional limit, and multiple product channels result, especially for reactions with the polyatomic molecules. Several reaction mechanisms are apparent, including charge transfer, proton transfer, and H-atom abstraction, although it is argued that many of the reactions proceed via a short-lived, ion–molecule complex which separates along the observed reaction channels. The NH3+ ions are seen to be generally less reactive than the lesser hydrogenated ions, the product of most of the reactions being HN4+ ions which do not undergo binary reactions with any of the molecules (except CH3NH2) but rather undergo ternary association reactions with a few of them. A few measurements were made using the deuterated analogs ND+, ND2+, ND3+, and ND4+ in order to shed further light on some of the reaction mechanisms.