N-cyclopentyl-1-(pyridin-2-yl)methanimine(dichloro)palladium(II) | 1548612-06-1

• 英文名称: N-cyclopentyl-1-(pyridin-2-yl)methanimine(dichloro)palladium(II)
• 英文别名: [(N-cyclopentyl-1-(pyridin-2-yl)methanimine)PdCl₂]
• CAS: 1548612-06-1
• 化学式: C₁₁H₁₄Cl₂N₂Pd
• 分子量: 351.572
• InChiKey: PRKCDSOHOZXSJO-HUDQUHEVSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  双(乙腈)氯化钯(II) 、 N-cyclopentyl-1-(pyridin-2-yl)methanimine 以 乙醇 为溶剂， 反应 12.0h， 以88%的产率得到N-cyclopentyl-1-(pyridin-2-yl)methanimine(dichloro)palladium(II)
  参考文献：
  名称：

  Palladium(II) complexes containing N,N′-bidentate N-cycloalkyl 2-iminomethylpyridine and 2-iminomethylquinoline: Synthesis, characterisation and methyl methacrylate polymerisation

  摘要：

  The reaction of [Pd(CH3CN)(2)Cl-2] with N-cyclopentyl-1-(pyridin-2-yl)methanimine (L-1), N-cyclohexyl-1-(pyridin-2-yl)methanimine (L-2), N-(piperidin-1-yl)-1-(pyridin-2-yl)methanimine (L-3) or N-cyclopentyl-1-(quinolin-2-yl)methanimine (L-4) in ethanol yields the bidentate (NN') PdCl2 complexes [L1PdCl2], [L2PdCl2], [L3PdCl2] and [L4PdCl2), respectively. The X-ray crystal structure of the Pd(II) complexes revealed that the Pd atom in [LnPdCl2] (L-n = L-1, L-2, L-3, L-4) shows a distorted square planar geometry involving two nitrogen atoms and two chloro ligands. The complexes [L1PdCl2] and [L4PdCl2] (of which the ligands are N-cyclopentyl substituted) showed the highest catalytic activity for the polymerisation of methyl methacrylate (MMA) in the presence of modified methylaluminoxane (MMAO) with an activity of 1.45 x 10(5) g PMMA/mol Pd h at 60 degrees C and a PMMA syndiotacticity (characterized using C-13 NMR spectroscopy) of ca. 0.70. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.11.036

文献信息

• Synthesis, characterization and antimicrobial properties of lipophilic palladium complexes bearing iminopyridine ligands
  作者：Patrick T. Gormley、B. Ninh Khuong、Courtney M. Dickie、Ashley M. Taweel、Heather L. Blundon、Josée-Marie E. J. Melanson、Adam F. LeBlanc、Tara S. Murphy、Curran G. Tompkins、Christopher M. Vogels、Andreas Decken、Felix J. Baerlocher、Tyson J. MacCormack、Stephen A. Westcott

  DOI：10.1007/s11243-015-9977-3

  日期：2015.11

  The reaction of [PdCl2(η2-coe)]2 (coe = cis-cyclooctene) with nine lipophilic iminopyridine ligands (NN′, 1a–i) afforded the corresponding metal complexes cis-[PdCl2(NN′)] (2a–i) with concomitant loss of the labile coe ligands. All iminopyridine complexes were characterized by physicochemical and spectroscopic methods. The molecular structures of two complexes, 2a and 2b, were determined by single

  [PdCl2(η2-coe)]2 (coe = cis-cyclooctene) 与九个亲脂性亚氨基吡啶配体 (NN', 1a-i) 反应得到相应的金属配合物 cis-[PdCl2(NN')] (2a-i ) 伴随着不稳定的 coe 配体的丢失。所有亚氨基吡啶配合物均通过物理化学和光谱方法表征。通过单晶 X 射线衍射研究确定了两种配合物 2a 和 2b 的分子结构。测试了所有复合物的潜在抗真菌和抗菌活性。