1,3-C6H4(CON(PdCl(C3H5)PPh2)CH2OPh)2 | 694439-45-7

• 英文名称: 1,3-C6H4(CON(PdCl(C3H5)PPh2)CH2OPh)2
• CAS: 694439-45-7
• 化学式: C₅₂H₄₈Cl₂N₂O₂P₂Pd₂
• 分子量: 1078.66
• InChiKey: YMBPUEDQSLYDNC-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  bis(η3-allyl-μ-chloropalladium(II)) 、 1,3-C₆H₄(CON(PPh₂)CH₂Ph)2 以 二氯甲烷 为溶剂， 以80%的产率得到1,3-C6H4(CON(PdCl(C3H5)PPh2)CH2OPh)2
  参考文献：
  名称：

  The preparation and coordination of 1,3-C6H4-{C(O)N(PPh2)CH2Ph}2 – a new multidentate ligand

  摘要：

  Reaction of isophthaloyl dichloride with two equivalents of benzylamine in the presence of Et3N gives N,N'-dibenzyl-1,3-isophthaldiamide which reacts with two equivalents of Ph2PCl, in the presence of n-BuLi at -78 degreesC to give 1,3-C6H4-{C(O)N(PPh2)CH2Ph}(2) (1). Reaction of 1 with [PtCl2(cod)] in dichloromethane gives the P,P',C tridentate bis-chelate [Pt(Cl){1,3-C6H4-{C(O)N(PPh2)CH2Ph}(2)}] (2), whilst reaction of 1 with two equivalents of [(C3H5)PdCl](2) in thf results in [{PdCl(C3H5)}(2) {1,3-C6H4-{C(O)N(PPh2)CH2Ph}(2)}] (3) in which the ligand bridges two palladium centres. The X-ray structures of 2 and 3 are reported. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2003.12.005