{12}-mercuracarborande-4 | 138233-74-6

• 英文名称: {12}-mercuracarborande-4
• 英文别名: [12]-mercuracarborand-4；12-mercuraborand-4
• CAS: 138233-74-6
• 化学式: C₈H₄₀B₄₀Hg₄
• 分子量: 1371.21
• InChiKey: VUEDYNSVIWNMRT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {12}-mercuracarborande-4 、 四丁基碘化铵 以 氘代丙酮 为溶剂， 生成 {12}-mercuracarborande-4*I2(2-)
  参考文献：
  名称：

  Yang, Xiaoguang; Johnson, Stephen E.; Khan, Saeed I., Angewandte Chemie, 1992, vol. 104, p. 886 - 889

  摘要：

  DOI：
• 作为产物：
  描述：

  在 CH₃COOAg 作用下， 以 乙醇 为溶剂， 以80%的产率得到{12}-mercuracarborande-4
  参考文献：
  名称：

  由碳硼烷支持的亲电子汞中心组成的一类新的大环多齿路易斯酸的主客体化学

  摘要：

  描述了包含亲电子汞中心的碳硼烷支持的大环家族的合成和表征。这些化合物是多齿路易斯酸，已被证明可以结合阴离子，例如 C1-、Br、I- 和 closo-BloHlo2- 以及不带电的亲核物质。阴离子复合物((1,2-C2BloH10Hg)&)Li,(l.XnLi,; X = C1, Br, n = 1; X = I, n = 1 or 2)的锂盐由反应合成Closo-1,2-Li~-l,2-C~B~~H~~ 与 HgX2（X = C1、Br 和 I），产率为 70-80%。游离主体(12lmercuracarborand-4(1)是用AgOAc从1.1~~-中去除卤离子得到的。l-CILi,(l.Br)z-(benzo(15)crown-5)的分子结构3-Liz(H2O)2 和 l*Iz(AsPh4)2 已从单晶 X 射线衍射研究中确定。1. ClLi 在四方空间群 P4/mcc 中结晶，a

  DOI：

  10.1021/ja00095a018

文献信息

• Yang, Xiaoguang; Knobler, Carolyn B.; Hawthorne, M. Frederick, Journal of the American Chemical Society, 1992, vol. 114, p. 380 - 382
  作者：Yang, Xiaoguang、Knobler, Carolyn B.、Hawthorne, M. Frederick

  DOI：——

  日期：——
• Supramolecular Inorganic Chemistry: Small Guests in Small and Large Hosts
  作者：Achim Müller、Hans Reuter、Stephan Dillinger

  DOI：10.1002/anie.199523281

  日期：1995.11.17

  AbstractA key reaction in the biological and material world is the controlled linking of simple (molecular) building blocks, a reaction with which one can create mesoscopic structures, which, for example, contain cavities and display specifically desired properties, but also compounds that exhibit typical solid‐state structures. The best example in this context is the chemistry of host–guest interactions, which spans the entire range from three‐ and two‐dimensional to one‐ and “zero‐dimensional”, discrete host structures. Members of the class of multidimensional compounds have been classified as such for a long time, for example, clathrates and intercalation compounds. Thus far, however, there are no classifications for discrete inorganic host–guest compounds. The first systematic approach can be applied to novel polyoxometalates, a class of compounds which has only recently become known. Molecular recognition; tailor‐made, molecular engineering; control of fragment linkage of spin organization and crystallization; cryptands and coronands as “cages” for cations, anions or anion–cation aggregates as sections of ionic lattices; anions within anions, receptors; host–guest interactions; complementarity, as well as the dialectic terms reduction and emergence are important terms and concepts of supramolecular inorganic chemistry. Of particular importance for future research is the comprehension of the mesoscopic area (molècular assemblies)—that between individual molecules and solids (“substances”)—which acts in the biological world as carrier of function and information and for which interesting material properties are expected. This area is accessible through certain variations of “controlled” self‐organization processes, which can be demonstrated by using examples from the chemistry of polyoxometalates. The comprehension of the laws that rule the linking of simple polyhedra to give complex systems enables one to deal with numerous interdisciplinary areas of research: crystal physics and chemistry, heterogeneous catalysis, bioinorganic chemistry (biomineralization), and materials science. In addition, conservative self‐organization processes, for example template‐directed syntheses, are of importance for natural philosophy in the context of the question about the inherent properties of material systems.
• Molecular Aggregates of Nitrate Ion with the Tetravalent Lewis Acid Host 12-Mercuracarborand-4:  Novel Trihapto Coordination of NO₃^-
  作者：Alfred A. Zinn、Carolyn B. Knobler、David E. Harwell、M. Frederick Hawthorne

  DOI：10.1021/ic9811244

  日期：1999.5.1