[PdClMe(5-Me-py-2-CHNEt)] | 1167576-63-7

• 英文名称: [PdClMe(5-Me-py-2-CHNEt)]
• CAS: 1167576-63-7
• 化学式: C₁₀H₁₅ClN₂OPd
• 分子量: 321.115
• InChiKey: ITZDNGASPQRYDX-DQMDRPASSA-M

反应信息

• 作为反应物：
  描述：

  silver tetrafluoroborate 、 [PdClMe(5-Me-py-2-CHNEt)] 、 乙腈 以 乙腈 为溶剂， 生成 [PdMe(acetonitrile)(5-MeO-py-2-CHNEt)](tetrafluoroborate)
  参考文献：
  名称：

  Binuclear Complexes of Bis-Chelating Ligands Based on [1,4]Dioxocino[6,5-b:7,8-b′]dipyridine Moieties

  摘要：

  Binucleating ligands based on a [1,4]dioxocino[6,5-b: 7,8 -b']dipyridine (doxpy) core were prepared and characterized. They all present two equal chelating moieties each one including one N, O, or S donor in addition to a pyridinic nitrogen. At least one d(8) ion (Pd-II or Pt-II) complex was prepared for each type of ligand. The stereochemical behavior of the ligands and the complexes, along with the cooperative catalytic ability of two Pd-II centers are discussed.

  DOI：

  10.1021/ic900239z
• 作为产物：
  描述：

  5-MeO-py-2-NCHNEt 、 [(PdClMe)2(μ-SMe2)2] 以 二氯甲烷 为溶剂， 生成 [PdClMe(5-Me-py-2-CHNEt)]
  参考文献：
  名称：

  Binuclear Complexes of Bis-Chelating Ligands Based on [1,4]Dioxocino[6,5-b:7,8-b′]dipyridine Moieties

  摘要：

  Binucleating ligands based on a [1,4]dioxocino[6,5-b: 7,8 -b']dipyridine (doxpy) core were prepared and characterized. They all present two equal chelating moieties each one including one N, O, or S donor in addition to a pyridinic nitrogen. At least one d(8) ion (Pd-II or Pt-II) complex was prepared for each type of ligand. The stereochemical behavior of the ligands and the complexes, along with the cooperative catalytic ability of two Pd-II centers are discussed.

  DOI：

  10.1021/ic900239z