dichloro[2-(2-pyridyl)imino-κN-N-(2-thiazolin-κN-2-yl)thiazolidine]zinc(II) | 412909-98-9

• 英文名称: dichloro[2-(2-pyridyl)imino-κN-N-(2-thiazolin-κN-2-yl)thiazolidine]zinc(II)
• CAS: 412909-98-9
• 化学式: C₁₁H₁₂Cl₂N₄S₂Zn
• 分子量: 400.671
• InChiKey: RGJKZZURYUQECH-MKQFFWQFSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-(2-Pyridinylimino)-3-(4,5-dihydrothiazol-2-yl)thiazolidine 、 zinc(II) chloride 以 乙醇 、 水 为溶剂， 以88.7%的产率得到dichloro[2-(2-pyridyl)imino-κN-N-(2-thiazolin-κN-2-yl)thiazolidine]zinc(II)
  参考文献：
  名称：

  The coordination chemistry of thiazoline/thiazolidine derivatives. II: synthesis and characterization of [CoCl2(PyTT)] and [ZnCl2(PyTT)] [PyTT=2-(2-pyridyl)imino-N-(2-thiazolin-2-yl)thiazolidine]

  摘要：

  The compounds dichloro[2-(2-pyridyl)imino-kappaN-N-(2-thiazolin-kappaN-2-yl)thiazolidine]cobalt(II) and dichloro[2-(2-pyridyl)imino-kappaN-N-(2-thiazolin-kappaN-2-yl)thiazolidine]zinc(II) have been isolated and characterized by single crystal X-ray diffraction and IR spectroscopy. Moreover, the cobalt(II) complex has been studied by means of magnetic susceptibility measurements and UV-Vis-NIR diffuse reflectance. Both complexes are isostructural. The environment around the cobalt(II) and zinc(II) atoms may be described as a distorted tetrahedral geometry with the metallic atoms coordinated to two chlorine atoms [Co-Cl(1) = 2.241(1) Angstrom: Co-Cl(2) = 2,2210) Angstrom]. [Zn-Cl(1) = 2.235(1) Angstrom: Zn-Cl(2) = 2.211(1) Angstrom]. one thiazoline nitrogen [Co-N(1) = 1.982(2) Angstrom], [Zn-N(1) = 2.021(2) Angstrom] and one imino nitrogen [Co-N(3) = 2.009(1) Angstrom], [Zn-N(3) = 2.056(2) Angstrom]. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00943-3