cis,trans,cis-[Rh(H)2(P(o-tolyl)3)2(MeOH)2]PF6 | 728023-63-0

• 英文名称: cis,trans,cis-[Rh(H)2(P(o-tolyl)3)2(MeOH)2]PF6
• CAS: 728023-63-0
• 化学式: C₄₄H₅₂O₂P₂Rh*F₆P
• 分子量: 922.713
• InChiKey: MHHOXRHWWUMFHD-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  cis,trans,cis-[Rh(H)2(P(o-tolyl)3)2(MeOH)2]PF6 、 N-苄烯丁胺 以 甲醇 为溶剂， 生成 cis-[Rh(P(p-tolyl)3)2(PhCH2N=CHPh)(PhCH2NH2)]PF6
  参考文献：
  名称：

  Imine Hydrolysis and Role of a Rhodium(I)−Imine−Amine Complex in Homogeneous H₂-Hydrogenation of the Imine and a Rare Example of Inequivalent NH₂ Protons

  摘要：

  A Rh-catalyzed, homogeneous hydrogenation of the imine, PhCH2N=CHPh, is shown to involve a Rh-imine-amine species that subsequently activates H-2, the amine (benzylamine) being formed via a Rh-catalyzed hydrolysis of the imine by adventitious water. The imine-amine complex, cis-{Rh[P(p-tolyl)(3)](2)(PhCH2N=CHPh)(NH2CH2Ph)}PF6 (2b), is structurally characterized, and the solution H-1 NMR data reveal inequivalent NH2 protons.

  DOI：

  10.1021/ic040037a